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At a given temperature the ratio of RMS ...

At a given temperature the ratio of RMS and average velocities is 

A

`1.086:1`

B

` 1:1.086`

C

`2:1.086`

D

` 1.086:2`

Text Solution

AI Generated Solution

The correct Answer is:
To find the ratio of the root mean square (RMS) velocity to the average velocity at a given temperature, we can follow these steps: ### Step 1: Understand the formulas for RMS and average velocity The RMS velocity (\(v_{rms}\)) and average velocity (\(v_{avg}\)) for a gas can be expressed as: - RMS velocity: \[ v_{rms} = \sqrt{\frac{3RT}{M_w}} \] - Average velocity: \[ v_{avg} = \sqrt{\frac{8RT}{\pi M_w}} \] Where: - \(R\) = universal gas constant - \(T\) = temperature in Kelvin - \(M_w\) = molecular weight of the gas ### Step 2: Set up the ratio of RMS velocity to average velocity We need to find the ratio: \[ \frac{v_{rms}}{v_{avg}} = \frac{\sqrt{\frac{3RT}{M_w}}}{\sqrt{\frac{8RT}{\pi M_w}}} \] ### Step 3: Simplify the ratio Since both expressions have common terms, we can simplify: \[ \frac{v_{rms}}{v_{avg}} = \sqrt{\frac{3RT}{M_w}} \cdot \sqrt{\frac{\pi M_w}{8RT}} = \sqrt{\frac{3\pi}{8}} \] ### Step 4: Calculate the numerical value Now we calculate the value of \(\sqrt{\frac{3\pi}{8}}\): 1. Calculate \(\pi \approx 3.14\). 2. Substitute \(\pi\) into the equation: \[ \sqrt{\frac{3 \cdot 3.14}{8}} = \sqrt{\frac{9.42}{8}} = \sqrt{1.1775} \approx 1.086 \] ### Step 5: Conclusion The ratio of RMS velocity to average velocity at a given temperature is approximately \(1.086\). Thus, the correct answer is: \[ \text{Ratio of } v_{rms} \text{ to } v_{avg} = 1.086 : 1 \] ### Final Answer The correct option is \(1.086 : 1\). ---
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