Home
Class 11
CHEMISTRY
A mixture containing 0.05 mol of K(2)Cr(...

A mixture containing 0.05 mol of `K_(2)Cr_(2)O_(7)` and 0.02 mol of `KMnO_(4)` was treated with excess of KI in acidic medium.The liberated iodine required 2.0 L of `Na_(2)SO_(3)` solution of titration. Concentration of `Na_(2)S_(2)O_(3)` solution was

A

`0.4 molL^(-1)`

B

`0.20 molL^(-1)`

C

`0.25 molL^(-1)`

D

`0.30 molL^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY

    NARENDRA AWASTHI|Exercise Level 2 (Q.1 To Q.30)|30 Videos
  • STOICHIOMETRY

    NARENDRA AWASTHI|Exercise Level 2 (Q.31 To Q.35)|5 Videos
  • STOICHIOMETRY

    NARENDRA AWASTHI|Exercise Level 1 (Q.151 To Q.180)|30 Videos
  • SOLID STATE

    NARENDRA AWASTHI|Exercise Level 3 - Subjective Problems|1 Videos
  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 3 - Match The Column|2 Videos

Similar Questions

Explore conceptually related problems

50 ml of given H_(2)O_(2) solution is added to excess KI solution in acidic medium. The liberated I_(2) required 20 ml of 0.04 M standard Hypo solution. Molarity of H_(2)O_(2) solution is

50 ml of given H_(2)O_(2) solution is added to excess KI solution in acidic medium. The liberated I_(2) requires 20 ml of 0.04 M standard Hypo solution. Molarity of H_(2)O_(2) solution is

Some amount of ..20V.. H_(2)O_(2) is mixed with excess of acidifeid solution KI. The iodine so liberated required 200ml of 0.IN Na_(2)S_(2)O_3 for tritration. The volume of H_2O_2 solution is

50 ml of given H_(2)O_(2) solution is added to excess KI solution in acidic medium. The liberated I_(2) requires 20 ml of 0.04 M standard Hypo solution. The strength of given 250 m H_(2)O_(2) solution is

Iodine titration can be iodemotire or iodimetric depending on using iodine directly or indirectly as an oxidising agent in the redox titration. a) Iodimetric titration in which a standard iodine solution is used as an oxidant and iodine is directly or indirectly titrated against a reducing agent. For example 2CuSO_(4)+4KIrarrCu_(2)I_(2)+2K_(2)SO_(4)+I_(2) b) Iodimetric procedures are used for the determination of strength of reducing agent such as thiosulphates, sulphites, arsenties and stannous chloride etc., by titrating them against standard solution of iodine in a burette. 2Na_(2)S_(2)O_(3)rarr2NaI+Na_(2)S_(4)O_(6) Starch is used as indicator near the end point which form blue colour complex with I_(3)^(-) . The blue colour disappeams when there is no more of free I_(2) . When 319.0 gm of CuSO_(4) in a solution is related with excess of 0.5 M KI solution, then librated iodine required 200 ml of 1.0 M Na_(2)S_(2)O_(3) for complete relation. The percentage purity of CuSO_(4) in the sample is

Iodine titration can be iodemotric or iodimetric depending on using iodine directly or indirectly is an oxidising agent in the redox titration. a. Iodimetric titration in which a standard iodine solution is used as an oxidant and iodine is directly or indirectly titrated against a reducing agent. For example. 2CuSO_(4)+4KJtoCu_(2)I_(2)+2K_(2)SO_(4)+I_(2) b. Iodimetric procedures are used for the datermination of strength of reducing agent such as thiosulphates, sulphites, arsenties adn stanous chloride etc. by titrating them against standard solution of iodine in a burette. 2Na_(2)SO_(3)to2 NaI +Na_(2)S_(4)O_(6) Starch is used as indicator near the end point whilch form blue colour complex with I_(3)^(-) . The blue colour disappeams when there is not more of free I_(2) . When 319.0 gm of CuSO_(4) in a solution is related with excess of 0.5 M KI solution, then librated iodine required 200 ml of 1.0M Na_(2)S_(2)O_(3) for complete relation. The percentage purity of CuSO_(4) in the sample is

There are two types of iodine titrations (a) Iodometric & (b) Iodimetric, Iodometric method is indirect method of I_(2) estimation. Any oxidant which liberates I_(2) from KI solution, the liberated iodine is estimated by titrating it with Na_(2)S_(2)O_(3) solution as : I_(2)+2Na_(2)S_(2)O_(3)rarr2NaI+Na_(2)S_(4)O_(6) 100 mL of .x. M K_(2)Cr_(2)O_(7) solution is added to excess of KI solution in acidic medium. The liberated iodine required 50 mL of 0.1N Na_(2)S_(2)O_(3) solution. The value of x is

One gram of a mixture of KMnO_(4) and K_(2)Cr_(2)O_(7) was treated with excess Kl in acid solution. The liberated iodine requred 200mL of 0.15N hypo for titration. Calculate the pracentage weight of potassium permanganate in the mixture.

50 ml of given H_(2)O_(2) solution is added to excess KI solution in acidic medium. The liberated I_(2) required 20 ml of 0.04 M standard Hypo solution. Weight of H_(2)O_(2) present in 250 ml of given solution is

NARENDRA AWASTHI-STOICHIOMETRY-Level 1 (Q.181 To Q.200)
  1. Calculate the mass of anhydrous oxalic acid, which can be oxidised to ...

    Text Solution

    |

  2. A mixture of K(2)C(2)O(4) and KHC(2)O(4) required equal volumes of 0.1...

    Text Solution

    |

  3. Stannous sulphate (SnSO(4)) and potassium permanganate are used as oxi...

    Text Solution

    |

  4. If x g is the mass of NaHC(2)O(4) required to neutralize 100 ml of 0.2...

    Text Solution

    |

  5. An equimolar mixture of Na(2)C(2)O(4) and H(2)C(2)O(4) required V(1)L ...

    Text Solution

    |

  6. A mixture containing 0.05 mol of K(2)Cr(2)O(7) and 0.02 mol of KMnO(4)...

    Text Solution

    |

  7. 5 ml of 1N HCl, 20 ml of N/2 H2SO4 and 30 ml of N/3 HNO3 are mixed tog...

    Text Solution

    |

  8. There are two types of iodine titrations (a) Iodometric & (b) Iodimetr...

    Text Solution

    |

  9. 1g mixture of equal number of mole of Li(2)CO(3) and other metal carbo...

    Text Solution

    |

  10. 32g of a sample of FeSO4 . 7H2O were dissolvedin dilute sulphuric acid...

    Text Solution

    |

  11. In the mixture of NaHCO(3) and NaCO(3), volume of a given HCl required...

    Text Solution

    |

  12. 0.1g of a solution containing Na2 CO3 and NaHCO3 requires 10mL of 0.01...

    Text Solution

    |

  13. In the mixture of NaHCO(3) and NaCO(3), volume of a given HCl required...

    Text Solution

    |

  14. When 200mL solution of NaOH and NaCO(3) was first titrated with N/10 H...

    Text Solution

    |

  15. 1gram of a sample of CaCO(3) was strongly heated and the CO(2) liberat...

    Text Solution

    |

  16. A sample of pure sodium carbonate 0.318g is dissolved in water and lit...

    Text Solution

    |

  17. 10L of hard water required 5.6g of lime for removing haardness. Hence ...

    Text Solution

    |

  18. 1L of pond water contains 20mg of Ca^(2+) and 12mg of mg^(2+) ions. Wh...

    Text Solution

    |

  19. One litre of a sample of hard water contain 4.44mg CaCl(2) and 1.9mg "...

    Text Solution

    |

  20. If hardness of water sample is 200ppm, then select the incorrect state...

    Text Solution

    |