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Oleum is considered as a solution of SO(...

Oleum is considered as a solution of `SO_(3)` in `H_(2)SO_(4)`, which is obtained by passing `SO_(3)` in solution of `H_(2)SO_(4)` When 100 g sample of oleum is diluted with desired mass of `H_(2)O` then the total mass of `H_(2)SO_(4)` obtained after dilution is known is known as % labelling in oleum.
For example, a oleum bottle labelled as '`109% H_(2)SO_(4)`' means the 109 g total mass of pure `H_(2)SO_(4)` will be formed when 100 g of oleum is diluted by 9 g of `H_(2)O` which combines with all the free `SO_(3)` present in oleum to form `H_(2)SO_(4)` as `SO_(3)+H_(2)O to H_(2)SO_(4)`
1 g of oleum sample is diluted with water. The solution required 54 mL of 0.4 N NaOH for complete neutralization. The % free `SO_(3)` in the sample is :

A

74

B

26

C

20

D

None of these

Text Solution

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The correct Answer is:
B
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NARENDRA AWASTHI-STOICHIOMETRY-Level 3 - Passage
  1. Oleum is considered as a solution of SO(3) in H(2)SO(4), which is obta...

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  2. Oleum is considered as a solution of SO(3) in H(2)SO(4), which is obta...

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  3. Oleum is considered as a solution of SO(3) in H(2)SO(4), which is obta...

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  4. Oleum is considered as a solution of SO(3) in H(2)SO(4), which is obta...

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  5. The strength of H(2)O(2) is expressed in several ways like molarity, n...

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  6. The strength of H(2)O(2) is expressed in several ways like molarity, n...

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  7. The strength of H(2)O(2) is expressed in several ways like molarity, n...

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  8. The strength of H(2)O(2) is expressed in several ways like molarity, n...

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  9. A water is said to be soft water if it produces sufficient foam with t...

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  10. (A) : Temporary hardness can be removed by boiling hard water (R) : ...

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  11. A water is said to be soft water if it produces sufficient foam with t...

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  12. "Equivalent mass" =("Molecular mass/Atomic mass" )/("n-factor") n-fa...

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  13. "Equivalent mass" =("Molecular mass/Atomic mass" )/("n-factor") n-fa...

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  14. "Equivalent mass" =("Molecular mass/Atomic mass" )/("n-factor") n-fa...

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  15. "Equivalent mass" =("Molecular mass/Atomic mass" )/("n-factor") n-fa...

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  16. Consider the following series of reactions : Cl(2)+2NaOH to NaCl+NaCl...

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  17. Consider the following series of reactions : Cl(2)+2NaOH to NaCl+NaCl...

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  18. Consider the following series of reactions : Cl(2)+2NaOH to NaCl+NaCl...

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