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If the lowest energy X-rays have lambda ...

If the lowest energy X-rays have `lambda = 3.055 xx 10^(-8)m`, estimate the minimum difference in energy between two Bohr.s orbits such that an electronic transition would correspond to emission of an X-ray. Assuming that the electrons in other shells exert no influence, at what Z(minimum) would a transition from the second energy level to the first result in the emission of an X-ray ?

A

1

B

2

C

3

D

4

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The only e^- in the H-atom resides under ordinary conditions on the first orbit when energy is supplied, the e^- moves to higher energy shells depending upon the amount of energy absorbed. When an e emits energy i.e., the e^- returns to the lowest energy state, from this Lyman, Balmer, Paschen, Bracket, Pfund series are there, so different spectral lines in the spectra of atoms correspond to different transitions of e^- s from higher to lower energy levels: In an hydrogen atom which of the following transition should be associated with highest absorption of energy

The only electron in the hydrogen atom resides under ordinary conditions on the first orbit. When energy is supplied, the electron moves to higher energy orbit depending on the amount of energy absorbed. When this electron returns to any of the lower orbits, it emits energy. Lyman series is formed when the electron returns to the lowest orbit while Balmer series is formed when the electron returns to second orbit. Similarly, Paschen, Brackett and Pfund series are formed when electron returns to the third, fourth orbits from higher energy orbits respectively (as shown in figure) Maximum number of lines produced when an electron jumps from nth level to ground level is equal to (n(n-1))/(2) . For example, in the case of n = 4, number of lines produced is 6. (4 rarr 3, 4 rarr 2, 4 rarr 1, 3 rarr 2, 3 rarr 1, 2 rarr 1) . When an electron returns from n_(2) to n_(1) state, the number of lines in the spectrum will be equal to ((n_(2) - n_(1))(n_(2)-n_(1) +1))/(2) If the electron comes back from energy level having energy E_(2) to energy level having energy E_(2) then the difference may be expressed in terms of energy of photon as E_(2) - E_(1) = Delta E, lambda = (h c)/(Delta E) . Since h and c are constant, Delta E corresponds to definite energy, thus each transition from one energy level to another will prouce a higher of definite wavelength. THis is actually observed as a line in the spectrum of hydrogen atom. Wave number of the line is given by the formula bar(v) = RZ^(2)((1)/(n_(1)^(2)) - (1)/(n_(2)^(2))) Where R is a Rydberg constant (R = 1.1 xx 10^(7)) (i) First line of a series : it is called .line of logest wavelength. or .line of shortest energy.. (ii) Series limit of last of a series : It is the line of shortest wavelength or line of highest energy. The difference in the wavelength of the 2^(nd) line of Lyman series and last line of Bracket series in a hydrogen sample is

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