For the auto-ionization of water at `25^(@)C, H_(2)O(l)iff H^(+)(aq)+OH^(-)` (aq) equilibrium constant is `10^(-14)`. What is `DeltaG^(@)` for the process?
A
`~=8xx10^(4)J`
B
`~=3.5xx10^(4)J`
C
`~=10^(4)J`
D
None of these
Text Solution
Verified by Experts
The correct Answer is:
A
`DeltaG^(@)=-RTln K_(w)` `=-8.314 xx 298 xx 2.303 (-14)` `~=80000J//"mol"`
Topper's Solved these Questions
THERMODYNAMICS
NARENDRA AWASTHI|Exercise Level 1 (Q.1 To Q.30)|6 Videos
THERMODYNAMICS
NARENDRA AWASTHI|Exercise Level 1 (Q.31 To Q.60)|2 Videos
The equilibrium constant for the ionisation of RNH_(2(g)) in water as RNH_(2(g)) + H_(2)O_((l)) hArr "RNH"_(3(aq))^(+) + OH_((aq))^(-) is 8 xx 10^(-6) at 25^(@) C . Find the pH of a solution at equilibrium when pressure of RNH_(2(g)) is 0.5 bar.
For the reaction Pt// H_2 (1 atm) // H^(+) (aq) // // Cl^(-) (aq) // AgCl // Ag , K_(c) (equilibrium constant ) is represented as
The E^@ at 25^@C for the following reaction is 0.22 V H_(2(g)) + 2AgCl_((s)) to 2Ag_((s)) + 2HCl_((aq)) . If the equilibrium constant at 25^@ C is 2.8 xx 10^(x) , x is
For the reaction 2H_(2)O_((l)) rarr H_(3)O_((aq))^(+) + OH_((aq))^(-) , the value of Delta H is
Enthalpy of neutralization is defined as the enthalpy change when 1 mole of acid/base is completely neutralized by base/acid in dilute solution. For strong acid and strong base neutralization net chemical change is H_((aq))^(+) + OH_((aq))^(-) rarr H_(2)O_((l)), Delta H_(r )^(0) -= - 55.84 kJ//mol What is Delta H^(0) for complete neutralisation of strong diacidic base A(OH)_(2) " by " HNO_(3) ?
i) H_3PO_(4(aq)) iff H^ _(aq)+ H_2PO_(4(aq))^- ii) H_2PO_(4(aq))^- iff H^ +(aq)+ H_2PO_(4(aq))^(2-) . iii) H_2PO_(4(aq))^(2-) iff H^ +(aq)+ PO_(4(aq))^(3-) . The equilibrium constantsfor the above reactions at a certain temperature are K_1, K_2 and K_3 respectively. The equilibrium constant for the reaction. H_3PO_4(aq) iff 3H^ +(aq)+ PO_(4(aq))^(3-) in terms K_1, K_2 and K_3 is
Calculate enthalpy of ionisation of OH^(-) ion. Given: H_(2)O_((l)) to H_((aq))^(+) + OH_((aq))^(-) , DeltaH^(@) = -285.83 KJ
NARENDRA AWASTHI-THERMODYNAMICS-Level 3 - Match The Column