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Gibbs Helmholtz equation relates the ent...

Gibbs Helmholtz equation relates the enthalpy, entropy and free energy change of the process at constant pressure and temperature as
`DeltaG=DeltaH-TDeltaS " (at constant P, T)"`
In General the magnitude of `DeltaH` does not change much with the change in temperature but the terms `TDeltaS` changes appreciably. Hence in some process spontaneity is very much dependent on temperature and such processes are generally known as entropy driven process.
Fro the reaction at 298 K, `A_(2)B_(4)rarr2AB_(2)`
`DeltaH=2" kJ"` and `DeltaS` = 20 J/K at constant P and T, the reaction will be

A

spontaneous and entropy driven

B

spontaneous and enthalpy driven

C

non-spontaneous

D

at equilibrium

Text Solution

Verified by Experts

The correct Answer is:
A

`(DeltaG)_(PT)=2000-(20xx298)`
`=-3960 " J"//"mol"`
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