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The S(N)2 reactivity order for halides i...

The `S_(N)2` reactivity order for halides is :

A

`R-F gt R-Cl gt R-Br gt R-I`

B

`R-I gt R -Br gt R-Cl gt R-F`

C

`R-Br gt R-I gt R-Cl gt R-F`

D

`R-C gt R- Br gt R- F gt R-I`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the `S_(N)2` reactivity order for halides, we need to analyze the stability of the leaving groups formed when halides participate in the `S_(N)2` reaction. The order of reactivity is influenced by the ability of the halide to act as a leaving group, which is related to the stability of the corresponding anion formed after the leaving group departs. ### Step-by-Step Solution: 1. **Identify the Halides**: The halides we are considering are fluorine (F), chlorine (Cl), bromine (Br), and iodine (I). 2. **Understand Leaving Group Ability**: The ability of a halide to act as a leaving group in an `S_(N)2` reaction is crucial. A better leaving group will increase the rate of the reaction. 3. **Electronegativity and Stability of Anions**: The stability of the anion formed after the halide leaves is important. The more electronegative an atom is, the less stable the negative charge is on it. This means: - Fluorine (F) is the most electronegative and thus forms a less stable anion (F⁻). - Iodine (I) is the least electronegative and forms a more stable anion (I⁻). 4. **Order of Leaving Group Ability**: Based on electronegativity and the stability of the corresponding anions, the leaving group ability increases down the group: - I⁻ > Br⁻ > Cl⁻ > F⁻ This means that I⁻ is the best leaving group and F⁻ is the worst. 5. **Reactivity Order for `S_(N)2` Reactions**: Since better leaving groups correlate with higher reactivity in `S_(N)2` reactions, we can establish the reactivity order for halides: - R-I > R-Br > R-Cl > R-F 6. **Final Answer**: Therefore, the `S_(N)2` reactivity order for halides is: - R-I > R-Br > R-Cl > R-F

To determine the `S_(N)2` reactivity order for halides, we need to analyze the stability of the leaving groups formed when halides participate in the `S_(N)2` reaction. The order of reactivity is influenced by the ability of the halide to act as a leaving group, which is related to the stability of the corresponding anion formed after the leaving group departs. ### Step-by-Step Solution: 1. **Identify the Halides**: The halides we are considering are fluorine (F), chlorine (Cl), bromine (Br), and iodine (I). 2. **Understand Leaving Group Ability**: The ability of a halide to act as a leaving group in an `S_(N)2` reaction is crucial. A better leaving group will increase the rate of the reaction. ...
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