Home
Class 12
CHEMISTRY
The order of reactivity of alkyl halide ...

The order of reactivity of alkyl halide in the reaction`R-X+Mg to RMgX` is :

A

`RI gt RBr gt RCl`

B

`RCl gt RBr gt RI`

C

`RBr gt RCl gt RI`

D

`RBr gt RI gt RCl`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of reactivity of alkyl halides in the reaction \( R-X + Mg \rightarrow RMgX \), we need to analyze the strength of the carbon-halogen bonds in different alkyl halides. The halides we are considering are iodine (I), bromine (Br), and chlorine (Cl). ### Step-by-Step Solution: 1. **Identify the Alkyl Halides**: We are looking at three types of alkyl halides: \( R-I \) (alkyl iodide), \( R-Br \) (alkyl bromide), and \( R-Cl \) (alkyl chloride). 2. **Understand Bond Strength**: The reactivity of these alkyl halides in the formation of Grignard reagents (\( RMgX \)) is influenced by the strength of the carbon-halogen bond. We can summarize the bond strengths as follows: - \( R-I \) bond is the weakest. - \( R-Br \) bond is stronger than \( R-I \) but weaker than \( R-Cl \). - \( R-Cl \) bond is the strongest. 3. **Relate Bond Strength to Reactivity**: The weaker the carbon-halogen bond, the more reactive the alkyl halide will be in forming the Grignard reagent. This is because a weaker bond is easier to break, allowing the magnesium to attach to the alkyl group. 4. **Rank the Alkyl Halides**: Based on the bond strengths: - \( R-I \) (weakest bond) will be the most reactive. - \( R-Br \) will be less reactive than \( R-I \) but more reactive than \( R-Cl \). - \( R-Cl \) (strongest bond) will be the least reactive. 5. **Final Order of Reactivity**: Therefore, the order of reactivity of alkyl halides in the reaction with magnesium is: \[ R-I > R-Br > R-Cl \] ### Conclusion: The correct answer for the order of reactivity of alkyl halides in the reaction \( R-X + Mg \rightarrow RMgX \) is \( R-I > R-Br > R-Cl \).

To determine the order of reactivity of alkyl halides in the reaction \( R-X + Mg \rightarrow RMgX \), we need to analyze the strength of the carbon-halogen bonds in different alkyl halides. The halides we are considering are iodine (I), bromine (Br), and chlorine (Cl). ### Step-by-Step Solution: 1. **Identify the Alkyl Halides**: We are looking at three types of alkyl halides: \( R-I \) (alkyl iodide), \( R-Br \) (alkyl bromide), and \( R-Cl \) (alkyl chloride). 2. **Understand Bond Strength**: The reactivity of these alkyl halides in the formation of Grignard reagents (\( RMgX \)) is influenced by the strength of the carbon-halogen bond. We can summarize the bond strengths as follows: - \( R-I \) bond is the weakest. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Assertion: The order of reactivity of alkyl halides towards S_(N^1) reaction in tertiary halidegtsecondary halidegtprimary halide. Reason: The reaction follows carbocation mechanism.

The order of reactivities of methyl halide in the formation of Grignard reagent is

For dehyetohalogenation, the order of reactivity of alkyl halides considering E1 mechanism is

The order of E_(2) elimination for alkyl halide is

Correct reactivity order of alkyl halides towards SN2 reaction is

Order of reactivity of hydrogen halides towards ethers is

The correct increasing order of the reactivity of halides for S_(N^(1)) reaction is:

The correct order of reactivity of hydrogen halides with ethyl alcohol is