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Vander waal's equation for 1 -mole He ga...

Vander waal's equation for 1 -mole He gas at high pressure can be written as:

A

`PV_(m)=RT-Pb`

B

`PV_(m)=RT+a/(V_(m))`

C

`PV_(m)=RT-a/(V_(m))`

D

`PV_(m)=RT+Pb`

Text Solution

Verified by Experts

The correct Answer is:
D

`(p+a/(V^(2)))(V_(m)-b)=RT`
`P gt gt a/(V^(2))`
`P(V_(m)-b)=RT`
`PV_(m)=RT+Pb`
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