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What will be the IUPAC name of ClHCH(2)C...

What will be the IUPAC name of `ClHCH_(2)C-="CC"H_(2)Br`?

A

1-Bromo-4-chlorobut-2-ene

B

1-Bromo-4-chlorobut-2-yne

C

1-Chloro-4-bromobut-2-ene

D

1-Chloro-4-bromobut-2-yne

Text Solution

Verified by Experts

The correct Answer is:
B

IUPAC name: 1-Bromo-4-chlorobut-2-yne
Rules of IUPAC nomenclature:
i. The longest carbon cahin is identified.
(ii) The parentchain is numbered so that the multiple bonds have the lowest numbers.
(iii) Halogen functional groups are prefixed with the bonding position and take the form fluoro-,chloro-,bromo-,iodo-,etc. depending on the halogen.
(iv)Sicne the double bond is equally distanct from either end and the halogen atoms are also equally distant from each end, the carbon attached to a halogen whose name comes first alphabetically would be given lowest numbered carbon in the continuous chain.
(v) Triple bonds in hydrocarbons are indicated by replacing the suffix -ane with -yne.
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