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N(2)O(4)(g)hArr2NO(2)(g) for the reactio...

`N_(2)O_(4)(g)hArr2NO_(2)(g)` for the reaction if the percentage dissociation of `N_(2)O_(4)` are 25%, 50%, 75% and 100% then the sequence of observed vapour densities will be `(d_(1),d_(2),d_(3)` and `d_(4)` are vapour density at 25%, 50%, 75% and 100% dissociation respectively)

A

`d_(1)gtd_(2)gtd_(3)gtd_(4)`

B

`d_(4)gtd_(3)gtd_(2)gtd_(1)`

C

`d_(1)=d_(2)=d_(3)=d_(4)`

D

`(d_(1)=d_(2))gt(d_(3)gtd_(4))`

Text Solution

Verified by Experts

The correct Answer is:
A

`alpha=(D-d)/((n-1)d)`
`alpha=(D-d)/d`
`d=D/(alpha+1)`
More `alpha` Less d
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