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During the electrolysis of molten lead b...

During the electrolysis of molten lead bromide which of the following takes place :

A

Bromide is released at the cathode

B

Lead is deposited at the anode

C

Bromide ions gain electrons

D

Lead is deposited at the cathode

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Electrolysis**: Electrolysis is a process that uses electrical energy to drive a non-spontaneous chemical reaction. In this case, we are looking at the electrolysis of molten lead bromide (PbBr₂). 2. **Setup of Electrolysis**: In the electrolysis setup, we have two electrodes: an anode (positive electrode) and a cathode (negative electrode). The lead bromide is molten, meaning it is in a liquid state and can conduct electricity. 3. **Dissociation of Lead Bromide**: When lead bromide is molten, it dissociates into its ions: - Lead ions (Pb²⁺) and bromide ions (Br⁻). 4. **Movement of Ions**: - The cations (Pb²⁺) move towards the cathode (negative electrode). - The anions (Br⁻) move towards the anode (positive electrode). 5. **Reactions at the Electrodes**: - **At the Anode**: Oxidation occurs. The bromide ions (Br⁻) lose electrons to form bromine gas (Br₂): \[ 2 \text{Br}^- \rightarrow \text{Br}_2 + 2 \text{e}^- \] - **At the Cathode**: Reduction occurs. The lead ions (Pb²⁺) gain electrons to form lead metal (Pb): \[ \text{Pb}^{2+} + 2 \text{e}^- \rightarrow \text{Pb} \] 6. **Final Products**: The products of the electrolysis of molten lead bromide are: - Bromine gas (Br₂) is released at the anode. - Lead metal (Pb) is deposited at the cathode. 7. **Conclusion**: From the options given in the question, the correct statement is that lead is deposited at the cathode.

**Step-by-Step Solution:** 1. **Understanding Electrolysis**: Electrolysis is a process that uses electrical energy to drive a non-spontaneous chemical reaction. In this case, we are looking at the electrolysis of molten lead bromide (PbBr₂). 2. **Setup of Electrolysis**: In the electrolysis setup, we have two electrodes: an anode (positive electrode) and a cathode (negative electrode). The lead bromide is molten, meaning it is in a liquid state and can conduct electricity. 3. **Dissociation of Lead Bromide**: When lead bromide is molten, it dissociates into its ions: - Lead ions (Pb²⁺) and bromide ions (Br⁻). ...
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