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Pure (S)-2-butanol has a specific rotati...

Pure (S)-2-butanol has a specific rotation of +13.52 degrees. A sample of 2-butanol prepared in the lab and purified by distillation has a calculated specific rotation of +6.76 degrees. What can you conclude about the composition ?

A

50% (S), 50% impurity

B

50% (S), 50% (R)

C

50% (S), 50% racemic

D

some other mixture

Text Solution

Verified by Experts

The correct Answer is:
C

Optical purity = `("Optical rotation of mixture")/("Optical rotation of pure compound") xx 100 , O.P. = (6.76)/(13.52) xx 100`
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MS CHOUHAN-ISOMERISM (STRUCTURAL & STEREOISOMERISM)-LEVEL 2 (SUBJECTIVE PROBLEMS)
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