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Examine the following formulas and selec...

Examine the following formulas and select those pairs that satisfy the following conditions: Be sure to write two letters (and only two) in each answer box, unless you select f. In the second and third parts more than one answer is possible.

Which are conformational isomers?

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(a & b) or ( a & d)
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Which of the following substituted benzene derivative would furnish three isomers when one more electrophilic substituent is introduced? Select the correct answer using the codes given below.

Which of the following substituted benzene derivative would furnish three isomers when one more electrophilic substituent is introduced? Select the correct answer using the codes given below.

Read the given information and answer the following questions. A survey was conducted in two villages, Vanaparthy and Vaddicherla of Warangal district in Telangana State. The first with no scarcity and the second with scarce groundwater. Well census was carried out in the villages in order to get a complete picture of well irrigation and its status as well as availability of water. There are no alternative sources of supply as against wells in Vaddicherla, where there is an existing tank that has been converted into a percolation tank, so that the water situation is much better in Vanaparthy. In which village, do you suggest drip irrigation ?

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition mush compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) the permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The spin-only magnetic moment of free ion is sqrt(8) B.M. The spin angular momentum of electron will be

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition must compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) the permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The orbital angular momentum of an electron in p-orbital makes an angle of 45^@ from Z-axis. Hence Z-component of orbital angular momentum of election is :

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition must compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) he permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The maximum orbital angular momentum of an electron with n= 5 is

Read the following statements and select the correct ones. i) All vertebrates are capable of osmoregulation and thermoregulation. ii) Some species have evolved the ability to regulate, but only over a limited range of environmental conditions, beyond which they simply conform. iii)99 per cent of animals and nearly all plants can- not maintain a constant internal environment. - iv)Animals arc either perfect regulators or perfect conformers.

The f-block consists of the two series lanthanoids and actinoids. Because Lanthanum closely resembles the Lanthanoids. The Lanthanoid resemble one another more closely than do the members ofordinary transition elements in any series. They have only one stable oxidation state. The chemistry of the actinoids is on the other hand, much more complicated. The complication arises partly owing to the occurance ofa wide range of oxidation states in these elements and partly because their radioactivity creates special problems in their study Wrong statement of the following is

The necessary condition for a molecule to exhibit optical isomerism is dissymmetry or chiral. Thus all organic compounds which contain one as symetric carbon atom are chiral and exist in two stereoisomers. Although the two forms have the same structure, they have different arrangements of groups about the as symmetric carbon. In fact, they represent as symetric molecules. They do not have a plane of symmetry. They are related to each other as an object to its mirror image and are non superimposable. The two structures actually stand for dextro or (+) and leavo or (-) isomers. Since they are related each other as mirror images, they are commonly called enantiomers. Which of the following statements is correct regarding compounds I to III

MS CHOUHAN-ISOMERISM (STRUCTURAL & STEREOISOMERISM)-LEVEL 2
  1. (i) 1,2-dichlorocyclopropane = w (ii) 1,3-dimethyl-cyclobutane = x ...

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  2. Examine the following formulas and select those pairs that satisfy the...

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  3. Examine the following formulas and select those pairs that satisfy the...

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  4. Examine the following formulas and select those pairs that satisfy the...

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  5. Examine the following formulas and select those pairs that satisfy the...

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  6. Examine the following formulas and select those pairs that satisfy the...

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  7. Examine the following formulas and select those pairs that satisfy the...

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  8. Consider the following statements regarding the given projection (True...

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  9. Consider the following statements regarding the given projection (True...

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  10. Consider the following statements regarding the given projection (True...

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  11. Consider the following statements regarding the given projection (True...

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  12. Examine the following structural formulas and select those that are ch...

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  13. The configuration of eight compounds, a through h are shown below, usi...

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  14. The configuration of eight compounds, a through h are shown below, usi...

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  15. The configuration of eight compounds, a through h are shown below, usi...

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  16. The configuration of eight compounds, a through h are shown below, usi...

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  17. The structural formula of ten compounds, (I) through (X) are drawn bel...

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  18. The structure of one of the enantiomers of the amino acid cysteine is ...

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  19. Identify the following double bonds either E, Z or None (N) in the com...

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  20. (a) Bongkrekic acid is a toxic compound produced by Pseudomonas cocove...

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