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Wolff rearrangement When alpha-Diazok...

Wolff rearrangement
When `alpha`-Diazoketones are photo-irradiated or heated at high temperature or reacted with silver oxide or silver salts at room temperature, they loose nitrogen and rearrange to form ketene.
The ketenes reacts rapidly with water, alcohol and amines. Therefore, the reactions called Wolff-rearrangement.

`Ph-underset(14)overset(O)overset(||)C-CHN_(2)underset(H_(2)O)overset(Ag_(2)O)to (A)` , Product (A) is :

A

`Ph-overset(14)(CH_(2))-CO_(2)H`

B

`Ph-CH_(2)-overset(14)(CO_(2))H`

C

`Ph-overset(14)(CO_(2))N`

D

`Ph-CO_(2)H`

Text Solution

Verified by Experts

The correct Answer is:
B
Intramolecular rearrangement
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