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Product (x) is :...

Product (x) is :

A

B

C

D

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The correct Answer is:
B



Since there is no carbonyl group in the first product, the double bond of the exocyclic methylene group has reacted with methylenephosphorane. We may therefore propose a mechanism based on the assumption that the exocyclic double bond behaves like the double bond in a carbonyl group. The latter reaction is

However, in the case under consideration, there is no oxygen atom, phosphine and not phosphine oxide is eliminated, and a single and not a double bond is formed with the methylene group. This can be accommodated by replacing `O^(-)` by ` gt C^(-)` (of the five - membered ring), and then as follows:

In this sequence, we have proposed a complete parallel with the carbonyl group and this results in the formation of a spiro-compound containing phosphorus in one ring. The final product is also a spiro-compound, but since this contains a three-membered ring, it could be argued that this is less stable than its precursor – which contains a four - membered ring. This can be overcome by assuming that the three - membered ring is formed directly, the mechanism involving neighbouring group participation i.e.,

This route would be energetically more favourable than the other one and so is the more likely one.
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MS CHOUHAN-HYDROCARBONS (ALKENES)-LEVEL-2
  1. Product (x) is :

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  2. In each reagent box write a letter designating the best reagent and co...

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  3. Propene (CH3 – CH = CH2) can be transformed to compounds (a to j) list...

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  4. In each reaction box write a single letter designating the best reagen...

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  5. Match the reagents a-j with products A-J. There is one best product fo...

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  6. Match the column :

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  7. Match the column I with column II and with column III (Matrix).

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  8. Match the column I and II.

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  9. Sum of molecular mass of A, B, C, D (i.e. A+B + C + D) is equal to :

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  10. underset("(all isomers) ")(C2FClBrl) underset(Ni) overset(H2)to (A)(ex...

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  11. Match the following columns

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  12. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  13. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  14. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  15. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  16. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  17. Vladimir Markovnikov rule : Alkenes undergo electrophilic addition rea...

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  18. CH3 - CH2-CH=CH2+CH2 OH overset(H^(o+))to CH3-CH2- underset(OCH3) un...

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  19. CH3 - CH2-CH=CH2+CH2 OH overset(H^(o+))to CH3-CH2- underset(OCH3) un...

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  20. CH3 - CH2-CH=CH2+CH2 OH overset(H^(o+))to CH3-CH2- underset(OCH3) un...

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  21. CH3 - CH2-CH=CH2+CH2 OH overset(H^(o+))to CH3-CH2- underset(OCH3) un...

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