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CH3 - CH2- overset(Br)overset(|)underset...

`CH_3 - CH_2- overset(Br)overset(|)underset(CH_2(n-Pr))underset(|)C-CH_3CH_2 - Et overset(alc. KOH)rarr underset("major")(A)`

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
C
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The monomer of the polymer [-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2)-]_(n)

CH_2 = CH - CH = underset(CH_3)underset(|)C-CH_3 overset(+HBr)to CH_3-overset(Br)overset(|)CH-CH = underset(CH_3)underset(|)C-CH_3 + underset((II))(CH_3 - CH ) = CH - underset(CH_3)underset(|)overset(Br)overset(|)C-CH_3 Correct statement about the above reaction is

In the given reaction sequence, CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)CH_(2)OH overset(K_(2)Cr_(2)O_(7),H_(2)SO_(4))underset(H_(2)O,Delta)to(A)overset(SOCl_(2))to(B)overset((CH_(3))_(2)NH)underset("mole")to(C)overset(1.LiAlH_(4))underset(2.H_(2)O)to(D)

Name the following compounds according to IUPAC system. (i) CH_(3) - CH_(2) - underset (CH_(2)Cl) underset(|)(CH) - overset (CH_(2)OH) overset(|) (CH) - underset (CH_(3)) underset (|) (CH) - CH_(3) CH_(3)- underset (CH_(3)) underset(|) (CH) -CH_(2) - underset(OH) underset(|) (CH) - overset (CH_(2)OH) overset(|) (CH) - CH_(2) (iii) (iv) H_(2)C = CH - underset (OH)underset (|) (CH) - CH_(2) - CH_(2) - CH_(3) (v) CH_(3) - underset (CH_(3)) underset ( |) C = underset (Br)underset(|) C - CH_(2)OH

CH_3 - CH_2 - overset(O ) overset(|| ) C - underset(CH_3) underset(|) overset(CH_3) overset(|) C- CH_3 overset(PhCO_2 H)to A , A will be

H_(3)C-CH_(2)-overset(CH_(3))overset(|)CH-underset(O)underset(||)C-NH_(2)overset(Br_(2)+KOH)underset(Delta)toA overset(1.CH_(3)"I(excess)")underset(2.AgOH,Delta)toB .

The IUPAC name of CH_(3)-CH_(2)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")("C ")-underset(C_(2)H_(5))underset("| ")("C ")=CH-CH_(3)

Monomer of (-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(2))_(n) is

CH_3-CH_2-overset(Br)overset(|)(C)H-CH_3underset(Delta)overset("Alcoholic KOH")(rarr) underset((I))(CH_3-CH_2-CH=CH_2)+underset((II))(CH_3-CH=CH-CH_3) Which of the following statement are correct 1) I is the major product of the reaction 2) II is the major product of the reaction 3) Formation of I is in accordance with Saytzeff rule. 4) II is more stable because it is more substituted