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Which of the following is not correctly ...

Which of the following is not correctly matched with its IUPAC name?

A

`CHF_(2)CBrClF` 1-Bromo-1-chloro-1, 2, 2-trifluoroethane

B

`(C Cl_(3))_(3)C Cl` 2-(Trichloromethyl)-1, 1,2,3, 3-heptachloropropane

C

`CH_(3)C(p-ClC_(6)H_(4))_(2)CH(Br)CH_(3)` 2-Bromo-3, 3-bis (4-chlorophenyl) butane

D

`0-BrC_(6)H_(4)CH(CH_(3))CH_(2)CH_(3)` 2-Bromo-l-methylpropylbenzene

Text Solution

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The correct Answer is:
To solve the question of which of the following is not correctly matched with its IUPAC name, we will analyze each option step by step. ### Step 1: Analyze Option A **Given Structure:** CHF2CBRCLF **Proposed IUPAC Name:** 1-Bromo-1-Chloro-1,2,2-Trifluoroethane 1. **Draw the structure:** The structure consists of a two-carbon chain (ethane) with various halogen substituents. 2. **Identify substituents:** - At carbon 1: Bromo (Br), Chloro (Cl), and Fluoro (F) groups. - At carbon 2: Two Fluoro (F) groups. 3. **Number the carbon atoms:** - Carbon 1: Bromo, Chloro, and one Fluoro. - Carbon 2: Two Fluoro. 4. **Write the name:** According to IUPAC nomenclature, the name should be: - 1-Bromo (Br) comes first (alphabetically). - 1-Chloro (Cl) follows. - 1,2,2-Trifluoro (F) follows. 5. **Final Name:** The correct IUPAC name is 1-Bromo-1-Chloro-1,2,2-Trifluoroethane, which matches the proposed name. ### Step 2: Analyze Option B **Given Structure:** C(CCl3)3CCl **Proposed IUPAC Name:** 2-Tri-Chloro-Methyl-1,1,1,2,3,3-Heptachloropropane 1. **Draw the structure:** The structure consists of a central carbon with three CCl3 groups and one CCl group. 2. **Identify substituents:** - At carbon 1: Three CCl3 groups. - At carbon 2: One CCl group. 3. **Number the carbon atoms:** - Carbon 1: Three CCl3 groups (total 9 Cl). - Carbon 2: One CCl group (1 Cl). 4. **Write the name:** The name should be: - 1,1,1-Trichloro (from three CCl3 groups). - 2-Chloro (from one CCl group). - Total: 7 Chlorine atoms, hence Heptachloro. 5. **Final Name:** The correct IUPAC name should be 1,1,1-Trichloro-2-Chloroheptachloropropane, which does not match the proposed name. ### Step 3: Analyze Option C **Given Structure:** C6H4-CH3 (para position) **Proposed IUPAC Name:** 2-Bromo-3,3-Bis(4-Chlorophenyl)butane 1. **Draw the structure:** The structure consists of a butane chain with a para-substituted chlorobenzene. 2. **Identify substituents:** - At carbon 2: Bromo group. - At carbon 3: Two para-chloro phenyl groups. 3. **Number the carbon atoms:** - Carbon 1: Butane backbone. - Carbon 2: Bromo. - Carbon 3: Two para-chloro phenyl groups. 4. **Write the name:** The name should be: - 2-Bromo (from carbon 2). - 3,3-Bis(4-Chlorophenyl) (from carbon 3). 5. **Final Name:** The correct IUPAC name matches the proposed name. ### Step 4: Analyze Option D **Given Structure:** C6H4-CH3 (ortho position) **Proposed IUPAC Name:** 2-Bromo-1-Methylpropylbenzene 1. **Draw the structure:** The structure consists of a propyl group attached to a benzene ring. 2. **Identify substituents:** - At carbon 1: Methyl group. - At carbon 2: Bromo group. 3. **Number the carbon atoms:** - Carbon 1: Methyl. - Carbon 2: Bromo. 4. **Write the name:** The name should be: - 2-Bromo (from carbon 2). - 1-Methyl (from carbon 1). 5. **Final Name:** The correct IUPAC name matches the proposed name. ### Conclusion The only option that is not correctly matched with its IUPAC name is **Option B**.

To solve the question of which of the following is not correctly matched with its IUPAC name, we will analyze each option step by step. ### Step 1: Analyze Option A **Given Structure:** CHF2CBRCLF **Proposed IUPAC Name:** 1-Bromo-1-Chloro-1,2,2-Trifluoroethane 1. **Draw the structure:** The structure consists of a two-carbon chain (ethane) with various halogen substituents. 2. **Identify substituents:** ...
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ICSE-SAMPLE PAPER 05 (CHEMISTRY)-MULTIPLE CHOICE QUESTIONS
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  9. The structure of Na(2)O, crystal is:

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  10. Ionic radii (in Å) of As^(3+), Sb^(3+) and Bi^(3+) follow the order :

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  11. Which of the following elements is most metallic?

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  12. An increase in equivalent conductance of a strong electrolyte with dil...

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  13. Aqeuous solution of which of the following compounds is the best condu...

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  14. How many kinds of space lattices are possible in a crystal?

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  15. The structure of MgO is similar to NaCl. What is the co- ordination...

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  17. Which of the following electrolytic solutions with the given concentra...

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