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Phenol is heated with CHCl(3) and alcoho...

Phenol is heated with `CHCl_(3)` and alcoholic KOH when salicylaldehyde is produced. This reaction is known as :

A

Rosenmund's reaction

B

Reimer-Tiemann reaction

C

Friedel-Craft's reaction

D

Sommelet reaction

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The correct Answer is:
To solve the question regarding the reaction of phenol with CHCl3 and alcoholic KOH to produce salicylaldehyde, we can break it down step by step: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol (C6H5OH), chloroform (CHCl3), and alcoholic potassium hydroxide (KOH). 2. **Understand the Reaction Conditions**: - The reaction takes place under heating conditions, which is essential for facilitating the reaction between phenol and chloroform in the presence of alcoholic KOH. 3. **Recognize the Type of Reaction**: - This reaction is a named reaction known as the "Reimer-Tiemann reaction." It involves the ortho-formylation of phenols. 4. **Mechanism Overview**: - In the presence of KOH, chloroform reacts to form a dichlorocarbene intermediate, which then attacks the ortho position of the phenol ring. This leads to the formation of salicylaldehyde (C6H4(OH)(CHO)). 5. **Identify the Product**: - The product formed from this reaction is salicylaldehyde, which has both a hydroxyl (OH) group and an aldehyde (CHO) group on the benzene ring. 6. **Conclusion**: - Therefore, the reaction of phenol with CHCl3 and alcoholic KOH to produce salicylaldehyde is known as the "Reimer-Tiemann reaction." ### Final Answer: The reaction is known as the **Reimer-Tiemann reaction**.
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