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Nature of aqueous solutions of two diffe...

Nature of aqueous solutions of two different amino acids X and Y are acidic and basic. Now X and Y can be:-
1. Cysteine and Lysine
2. Arginine and Lysine
3. Aspartic acid and Arginine
4. All of these

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An amino acid is characterized by two pKa values the one corresponding to the more acidic site is designated as pKa_1 and the other corresponding to the less acidic site is designated as pKa_2 The isoelectric point also called isoionic point (pI) is the pH at which concentration of zwitter ion is maximum . pI is the average of pKa_1 and pKa_2 .Generally the value of pI is slightly less than 7. some amino acids have side chain with acidic or basic groups.These amino acids have pKa_3 value also for the side chain.Acidic amino acid have acidic side chains and basic amino acids have basic side chains . pI for acidic amino acid is average of pKa_1 and pKa_3 .pI for basic amino acid is the average of pKa_2 and pKa_3 . {:(S.NO,"Amino acid",p^(Ka1),p^(Ka2),p^(Ka3)("side chain")),(I,"Aspartic acid",1.88,9.6,3.65),(II,"Glutamic acid",2.19,9.67,4.25),(III,"Lysine",2.18,8.95,10.53),(IV,"Arginine",2.17,9.04,12.48):} In the table given above the acidic amino acids are

There are three containers of equal capacity and all are completely filled with mixtures of acid and water in different ratios. The ratio of acid to water in the first container is 2 : 3, in the second container the ratio is 3:7 and in the third container it is 4:11. If the mixtures of all the three containers are mixed together, what will be the ratio of acid to water in it?

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound X is

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Y is

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Z is