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When SO2 gas is passed through acidified...

When `SO_2` gas is passed through acidified `K_2Cr_2O_7` solution, the colour of the solution changes to:

A

Red

B

Black

C

Orange

D

Green

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to understand the reaction that occurs when sulfur dioxide (SO₂) gas is passed through an acidified potassium dichromate (K₂Cr₂O₇) solution. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have sulfur dioxide (SO₂) and acidified potassium dichromate (K₂Cr₂O₇). The potassium dichromate is in an acidic medium, which is typically sulfuric acid (H₂SO₄). 2. **Understand the Oxidation States**: - In K₂Cr₂O₇, chromium (Cr) is in the +6 oxidation state. - In the product chromium(III) sulfate (Cr₂(SO₄)₃), chromium is in the +3 oxidation state. - In SO₂, sulfur (S) is in the +4 oxidation state, and when it is oxidized to sulfuric acid (H₂SO₄), sulfur is in the +6 oxidation state. 3. **Write the Balanced Reaction**: - The reaction can be summarized as follows: \[ SO_2 + K_2Cr_2O_7 + H_2SO_4 \rightarrow Cr_2(SO_4)_3 + K_2SO_4 + H_2O \] - Here, SO₂ is oxidized to H₂SO₄, and K₂Cr₂O₇ is reduced to Cr₂(SO₄)₃. 4. **Color Change Observation**: - Potassium dichromate (K₂Cr₂O₇) is orange in color due to the presence of Cr⁶⁺ ions. - When it is reduced to Cr³⁺ ions in chromium(III) sulfate (Cr₂(SO₄)₃), the solution turns green. 5. **Conclusion**: - Therefore, when SO₂ gas is passed through acidified K₂Cr₂O₇ solution, the color of the solution changes from orange to green. ### Final Answer: The color of the solution changes to green. ---
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