Which of the following statements is incorrect regarding physiosorption?
1.It involves vander waals forces.
2.More easily liquifiable gases are adsorbed readily.
3.Under high pressure it results into multi molecular layer of absorbate on adsorbent surface.
4.Enthalpy of adsorption is low and positive.

Which statement is correct when adsorption of gas take place on metal surface? (a) delta H becomes less negative with pregress of reaction. (b) with progress of reaction the strength of residual forces increases. (c) NH_3 is adsorbed more than N_2 . (d) Equilibrium concentration of adsorbate increases with increase in temperature.

Only the surface atoms in an adsorbent play an active role in adsorption. These atoms possess some residual force such as van der Waals forces and chemical forces. In the process of adsorption. Weak adsorbate is substituting by strong adsorbete. Activated charcoal used in the gas mask is already exposed to the atmospheric air, so gases and water vapours in air are adsorbed on its surface. When the mask is exposed to chlorine atmosphere, the gases are displaced by chlorine. In general, easily liquefiable gases such as CO_(2),NH_(3),Cl_(2), and SO_(2) are adsorbed to a greater extent than the elemental gases, e.g., H_(2),N_(2),O_(2), He, etc. In physical adsorption, the forces associated are

Out of the following gases which will be adsorbed more readily on the surface of charcoal : NH_3 gt CO_2 gt O_2

Only the surface atoms in an adsorbent play an active role in adsorption. These atoms possess some residual force such as van der Waals forces and chemical forces. In the process of adsorption. Weak adsorbate is substituting by strong adsorbete. Activated charcoal used in the gas mask is already exposed to the atmospheric air, so gases and water vapours in air are adsorbed on its surface. When the mask is exposed to chlorine atmosphere, the gases are displaced by chlorine. In general, easily liquefiable gases such as CO_(2),NH_(3),Cl_(2), and SO_(2) are adsorbed to a greater extent than the elemental gases, e.g., H_(2),N_(2),O_(2), He, etc. Gas mask works on the principle of

Only the surface atoms in an adsorbent play an active role in adsorption. These atoms possess some residual force such as van der Waals forces and chemical forces. In the process of adsorption. Weak adsorbate is substituting by strong adsorbete. Activated charcoal used in the gas mask is already exposed to the atmospheric air, so gases and water vapours in air are adsorbed on its surface. When the mask is exposed to chlorine atmosphere, the gases are displaced by chlorine. In general, easily liquefiable gases such as CO_(2),NH_(3),Cl_(2), and SO_(2) are adsorbed to a greater extent than the elemental gases, e.g., H_(2),N_(2),O_(2), He, etc. Which of the following gases will substitute O_(2) from adsorbed charcoal?

The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressure and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas behaviour as compared to the gases which are liquified with difficulty. The van der Waals equation reduces itself to ideal gas equation at

Which of the following statements are incorrect ? (1) Co^(+3) with strong field ligand forms high magnetic moment complex. (2) For Co^(+3) if pairing "energy"(P) gt Delta_o then the complex formed will have (t_(2g)^(4),(e_g)^2) configuration. (3) For [Co(en)^3]^( 3+) lambda_("absorbed") is less than lambda_("absorbed") for [CoF_6]^( 3–) (4) If Delta_o = 18000 cm^(–1) for Co^(+3) then with same ligands for it Delta_t = 16000 cm^(–1)

The distribution of electrons among molecular orbitals is called the electronic configuration of the molecule which provides us the following very important informations about the molecule. (A)Stability of molecule : The molecule is stable if number of bonding moleculer orbital electrons (N_b) is greater than the number of antibonding molecular orbital electrons (N_a) . (B) Bond order : Bond order =1/2(N_b-N_a) A positive bond order means a stable molecule while a negative or zero bond order means an unstable molecule. ( C)Nature of the bond : Bond order 1,2 and 3 corresponds to single , double and triple bonds respectively. (D)Bond length: Bond length decreases as bond order increases. (E)Magnetic nature: Molecular orbitals in a molecule are doubly occupied , the substance is diamagnetic and if one or more molecular orbitals are singly occupied, it is paramagnetic. Which of the following statements is incorrect ?

The word fluid means a substance having particles which readily of its magnitude (a small shear stress, which may appear to be of negligible will cause deformation in the fluid). Fluids are charactrised by such properties as density. Specific weight, specific gravity, viscosity etc. Density of a substance is defined as mass per unit volume and it is denoted by. The specific gravity represents a numerical ratio of two densities, and water is commonly taken as a reference substance. Specific gravity of a substance in written as the ratio of density of substance to the density of water. Specific weight represents the force exerted by gravity on a unit volume of fluid. It is related to the density as the product of density of a fluid and acceleration due to gravity. Viscosity is the most important and is recognized as the only single property which influences the fluid motion to a great extent. The viscosity is the property by virtue of which a fluid offers resistance to deformation under the influenece if shear force. The force between the layers opposing relative motion between them are known as forces of viscosity. When a boat moves slowly on the river remains at rest. Velocities of different layers are different. Let v be the velocity of the level at a distance y from the bed and V+dv be the velocity at a distance y+dy . The velocity differs by dv in going through a distance by perpendicular to it. The quantity (dv)/(dy) is called velocity gradient. The force of viscosity between two layers of a fluid is proportional to velocity gradient and Area of the layer. F prop A & F prop (dv)/(dy) F= -etaA(dv)/(dy) ( -ve sign shown the force is frictional in nature and opposes relative motion. eta coefficient of dynamic viscosity Shear stress (F)/(A)= -eta(dv)/(dy) and simultaneously kinematic viscosity is defined as the dynamic viscosity divided by the density. If is denoted as v . The viscosity of a fluid depends upon its intermolecular structure. In gases, the molecules are widely spaced resulting in a negligible intermolecular cohesion, while in liquids the molecules being very close to each other, the cohesion is much larger with the increases of temperature, the cohesive force decreases rapidly resulting in the decreases of viscosity. In case of gases, the viscosity is mainly due to transfer of molecular momentum in the transerve direction brought about by the molecular agitation. Molecular agitation increases with rise in temperature. Thus we conclude that viscosity of a fluid may thus be considered to be composed of two parts, first due to intermolecuar cohesion and second due to transfer of molecular momentum. If the velocity profile is given by v=(2)/(3)y-y^(2)v is velocity in m//sec y is in meter above the bad. Determine shear stress at y=0.15m , & eta=0.863 Ns//m^(2)

When an object moves through a fluid, as when a ball falls through air or a glass sphere falls through water te fluid exerts a viscous foce F on the object this force tends to slow the object for a small sphere of radius r moving is given by stoke's law, F_(w)=6pietarv . in this formula eta in the coefficient of viscosity of the fluid which is the proportionality constant that determines how much tangential force is required to move a fluid layer at a constant speed v, when the layer has an area A and is located a perpendicular distance z from and immobile surface. the magnitude of the force is given by F=etaAv//z . For a viscous fluid to move from location 2 to location 1 along 2 must exceed that at location 1, poiseuilles's law given the volumes flow rate Q that results from such a pressure difference P_(2)-P_(1) . The flow rate of expressed by the formula Q=(piR^(4)(P_(2)-P_(1)))/(8etaL) poiseuille's law remains valid as long as the fluid flow is laminar. For a sfficiently high speed however the flow becomes turbulent flow is laminar as long as the reynolds number is less than approximately 2000. This number is given by the formula R_(e)=(2overline(v)rhoR)/(eta) In which overline(v) is the average speed rho is the density eta is the coefficient of viscosity of the fluid and R is the radius of the pipe. Take the density of water to be rho=1000kg//m^(3) Q. If the sphere in previous question has mass of 1xx10^(-5)kg what is its terminal velocity when falling through water? (eta=1xx10^(-3)Pa-s) A. 1.3m/s B. 3.4m/s C. 5.2m/s D. 6.5m/s