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Which of the following sets of quantum n...

Which of the following sets of quantum numbers is not possible?
`n=5,l=2,m=-1,s=+(1)/(2)`
`n=5,l=2,m=2,s=+(1)/(2)`
`n=5,l=1,m=2,s=-(1)/(2)`
`n=5,l=1,m=-1,s=-(1)/(2)`

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