Identify the incorrect statement about halogens. qquad F_(2) is the best oxidant & non metal with highest S.R.P value The only halogen that oxidises water is Cl_(2) The halogen that occurs in liquid state at 25^(0)C is Br_(2) Among all halogens ^(I_(2)) having strong Vander waals forces among its molecules.

Statement-1: All halogens are coloured. Statement-2: Halogens exist in diatomic gaseous state. Statement-3: F_(2) is more reactive than Cl_(2)

Which of the statement is/are true about the reactivity of halogenation of alkanes ? The reactivity ordar is F_(2) gt C1_(2) gt Br_(2) gt I_(2) . I. Lower the activation energy for the chain initiation step, more reactive is the halogen. II. Lower the activation energy for the first chain propagation step, more reactive is the halogen. III. More negative is the overall heat of the reaction (Delta H_(r)^(@)) of halogenation ofg alkane, more reactive is the halogen. IV. Lower the activation energy for the second chain-propagation step, more reactives is the halogen.

Three identical capacitors C_(1),C_(2) and C_(3) have a capacitance of 1.0 mu F each and they are uncharged initially. They are connected in a circuit as shown in the figure and C_(1) is then filled completely with a dielectric material of relative permittivity epsilon_(r) . The cell electromotive force (emf) V_(0)=8V . First the switch S_(1) is closed while the switch S_(2) is kept open. When the capacitor C_(3) is fully charged, S_(1) is opened and S_(2) is closed simultaneously. When all the capacitors reach equilibrium, the charge on C_(3) is found to be 5 mu c . The value of epsilon_(r) = ____________.

It is not possible to measure the atomic radius precisely since the electron cloud surrounding the atom does not have a sharp boundary. One practical approach to estimate the size of an atom of a non-metallic element is to measure the distance between two atoms when they are bound together by a single bond in a covalent molecule and then dividing by two. For metals we define the term "metallic radius" which is taken as half the inter nuclear distance separating the metal cores in the metallic crystal. Then van der waal's radius represents the over all size of the atoms which includes its valence shell in a non bonded situation. It is the half of the distance between two similar atoms in separate molecules in a solid. The atomic radius decreases across a period and increases down the group. Same trends are observed in case of ionic radius. Ionic radius of the species having same number of electrons depends on the number of protons in their nuclei. Sometimes, atomic and ionic radii give unexpected trends due to poor shielding of nuclear charge by d -and f- orbital electrons. Now answer the following three questions: K^(+), CI^(-), Ca^(2+), S^(2-) ions are isoelectronic. The decreasing order of their size is:

The periodicity is related to the electronic configuration. That is, all chemical and phyical properties are a manifestation of the electronic configurfation of the elements. The atomic and ionic radii generally decrease in a preiod from left or right. As a consequence , the ionisation enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionisation enthalpy of the extreme left element in a period is the least and the electron left element on the extreme right is the highest negative. This results into high chemical reactivity at two extgremes and the lowest in the centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease (with excetption in some third period elements) in electron gain enthalpies in the case of main group elements . These properties can be related with the (i) reducing and oxidising behacviour of the elements (ii) metallic and no-metallic charcter of element (iii) acidic, basic , amphoteric and neutral character of the oxides of the elements. Among Al_(2)O_(3), SiO_(2),P_(2)O_(3) and SO_(2) the correct order of acid strenght is :

Direction : Resistive force proportional to object velocity At low speeds, the resistive force acting on an object that is moving a viscous medium is effectively modeleld as being proportional to the object velocity. The mathematical representation of the resistive force can be expressed as R = -bv Where v is the velocity of the object and b is a positive constant that depends onthe properties of the medium and on the shape and dimensions of the object. The negative sign represents the fact that the resistance froce is opposite to the velocity. Consider a sphere of mass m released frm rest in a liquid. Assuming that the only forces acting on the spheres are the resistive froce R and the weight mg, we can describe its motion using Newton's second law. though the buoyant force is also acting on the submerged object the force is constant and effect of this force be modeled by changing the apparent weight of the sphere by a constant froce, so we can ignore it here. Thus mg - bv = m (dv)/(dt) rArr (dv)/(dt) = g - (b)/(m) v Solving the equation v = (mg)/(b) (1- e^(-bt//m)) where e=2.71 is the base of the natural logarithm The acceleration becomes zero when the increasing resistive force eventually the weight. At this point, the object reaches its terminals speed v_(1) and then on it continues to move with zero acceleration mg - b_(T) =0 rArr m_(T) = (mg)/(b) Hence v = v_(T) (1-e^((vt)/(m))) In an experimental set-up four objects I,II,III,IV were released in same liquid. Using the data collected for the subsequent motions value of constant b were calculated. Respective data are shown in table. {:("Object",I,II,II,IV),("Mass (in kg.)",1,2,3,4),(underset("in (N-s)/m")("Constant b"),3.7,1.4,1.4,2.8):} If an object of mass 2 kg and constant b = 4 (N-s)/(m) has terminal speed v_(T) in a liquid then time required to reach 0.63 v_(T) from start of the motion is :

Direction : Resistive force proportional to object velocity At low speeds, the resistive force acting on an object that is moving a viscous medium is effectively modeleld as being proportional to the object velocity. The mathematical representation of the resistive force can be expressed as R = -bv Where v is the velocity of the object and b is a positive constant that depends onthe properties of the medium and on the shape and dimensions of the object. The negative sign represents the fact that the resistance froce is opposite to the velocity. Consider a sphere of mass m released frm rest in a liquid. Assuming that the only forces acting on the spheres are the resistive froce R and the weight mg, we can describe its motion using Newton's second law. though the buoyant force is also acting on the submerged object the force is constant and effect of this force be modeled by changing the apparent weight of the sphere by a constant froce, so we can ignore it here. Thus mg - bv = m (dv)/(dt) rArr (dv)/(dt) = g - (b)/(m) v Solving the equation v = (mg)/(b) (1- e^(-bt//m)) where e=2.71 is the base of the natural logarithm The acceleration becomes zero when the increasing resistive force eventually the weight. At this point, the object reaches its terminals speed v_(1) and then on it continues to move with zero acceleration mg - b_(T) =0 rArr m_(T) = (mg)/(b) Hence v = v_(T) (1-e^((vt)/(m))) In an experimental set-up four objects I,II,III,IV were released in same liquid. Using the data collected for the subsequent motions value of constant b were calculated. Respective data are shown in table. {:("Object",I,II,II,IV),("Mass (in kg.)",1,2,3,4),(underset("in (N-s)/m")("Constant b"),3.7,1.4,1.4,2.8):} If buoyant force were also taken into account then value of terminal speed would have

Direction : Resistive force proportional to object velocity At low speeds, the resistive force acting on an object that is moving a viscous medium is effectively modeleld as being proportional to the object velocity. The mathematical representation of the resistive force can be expressed as R = -bv Where v is the velocity of the object and b is a positive constant that depends onthe properties of the medium and on the shape and dimensions of the object. The negative sign represents the fact that the resistance froce is opposite to the velocity. Consider a sphere of mass m released frm rest in a liquid. Assuming that the only forces acting on the spheres are the resistive froce R and the weight mg, we can describe its motion using Newton's second law. though the buoyant force is also acting on the submerged object the force is constant and effect of this force be modeled by changing the apparent weight of the sphere by a constant froce, so we can ignore it here. Thus mg - bv = m (dv)/(dt) rArr (dv)/(dt) = g - (b)/(m) v Solving the equation v = (mg)/(b) (1- e^(-bt//m)) where e=2.71 is the base of the natural logarithm The acceleration becomes zero when the increasing resistive force eventually the weight. At this point, the object reaches its terminals speed v_(1) and then on it continues to move with zero acceleration mg - b_(T) =0 rArr m_(T) = (mg)/(b) Hence v = v_(T) (1-e^((vt)/(m))) In an experimental set-up four objects I,II,III,IV were released in same liquid. Using the data collected for the subsequent motions value of constant b were calculated. Respective data are shown in table. {:("Object",I,II,II,IV),("Mass (in kg.)",1,2,3,4),(underset("in (N-s)/m")("Constant b"),3.7,1.4,1.4,2.8):} At the start of motion when object is released in the liquid, its acceleration is :

Direction : Resistive force proportional to object velocity At low speeds, the resistive force acting on an object that is moving a viscous medium is effectively modeleld as being proportional to the object velocity. The mathematical representation of the resistive force can be expressed as R = -bv Where v is the velocity of the object and b is a positive constant that depends onthe properties of the medium and on the shape and dimensions of the object. The negative sign represents the fact that the resistance froce is opposite to the velocity. Consider a sphere of mass m released frm rest in a liquid. Assuming that the only forces acting on the spheres are the resistive froce R and the weight mg, we can describe its motion using Newton's second law. though the buoyant force is also acting on the submerged object the force is constant and effect of this force be modeled by changing the apparent weight of the sphere by a constant froce, so we can ignore it here. Thus mg - bv = m (dv)/(dt) rArr (dv)/(dt) = g - (b)/(m) v Solving the equation v = (mg)/(b) (1- e^(-bt//m)) where e=2.71 is the base of the natural logarithm The acceleration becomes zero when the increasing resistive force eventually the weight. At this point, the object reaches its terminals speed v_(1) and then on it continues to move with zero acceleration mg - b_(T) =0 rArr m_(T) = (mg)/(b) Hence v = v_(T) (1-e^((vt)/(m))) In an experimental set-up four objects I,II,III,IV were released in same liquid. Using the data collected for the subsequent motions value of constant b were calculated. Respective data are shown in table. {:("Object",I,II,II,IV),("Mass (in kg.)",1,2,3,4),(underset("in (N-s)/m")("Constant b"),3.7,1.4,1.4,2.8):} Which object has greatest terminal speed in the liquid ?

Direction : Resistive force proportional to object velocity At low speeds, the resistive force acting on an object that is moving a viscous medium is effectively modeleld as being proportional to the object velocity. The mathematical representation of the resistive force can be expressed as R = -bv Where v is the velocity of the object and b is a positive constant that depends on the properties of the medium and on the shape and dimensions of the object. The negative sign represents the fact that the resistance froce is opposite to the velocity. Consider a sphere of mass m released frm rest in a liquid. Assuming that the only forces acting on the spheres are the resistive froce R and the weight mg, we can describe its motion using Newton's second law. though the buoyant force is also acting on the submerged object the force is constant and effect of this force be modeled by changing the apparent weight of the sphere by a constant froce, so we can ignore it here. Thus mg - bv = m (dv)/(dt) rArr (dv)/(dt) = g - (b)/(m) v Solving the equation v = (mg)/(b) (1- e^(-bt//m)) where e=2.71 is the base of the natural logarithm The acceleration becomes zero when the increasing resistive force eventually the weight. At this point, the object reaches its terminals speed v_(1) and then on it continues to move with zero acceleration mg - b_(T) =0 rArr m_(T) = (mg)/(b) Hence v = v_(T) (1-e^((vt)/(m))) In an experimental set-up four objects I,II,III,IV were released in same liquid. Using the data collected for the subsequent motions value of constant b were calculated. Respective data are shown in table. {:("Object",I,II,II,IV),("Mass (in kg.)",1,2,3,4),(underset("in (N-s)/m")("Constant b"),3.7,1.4,1.4,2.8):} Which object would first acquire half of their respective terminal speed in minimum time from start of the motion of all were released simultaneously ?