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Major products formed by heating (CH(3))...

Major products formed by heating `(CH_(3))_(3)C-O-CH_(2)-CH_(3)` with HI are :
(a) `(CH_(3))_(3)C-I` and `CH_(3)CH_(2)OH`
(b) `(CH_(3))_(3)C-OH` and `CH_(3)CH_(2)I`
(c) ` (CH_(3))_(3)C-I` and `CH_(3)CH_(2)I`
(d) `(CH_(3))_(3)C-OH` and `CH_(3)CH_(2)OH`

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(CH_(3))_(3)C-OCH_(3) on reaction with HI gives (CH_(3))_(3)C-I and CH_(3)-OH as the main products and not (CH_(3))_(3)C-OH and CH_(3)-I . Explain.

Predict the major product of dehydration of each of (A). (CH_(3))_(2)C(OH)CH_(2)CH_(3) (B). (CH_(3))_(2)CHCH(OH)CH_(3) (C). (CH_(3))C(OH)CH(CH_(3))_(2)

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

Hydroboration-Oxidation of CH_(3)CH=CH_(2) produces (1). CH_(3)CH_(2)CH_(2)OH (2). CH_(3)CH(OH)CH_(2) (3). CH_(3)CH(OH)CH_(2)OH (4). CH_(3)COCH_(3)