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Class 8 Maths Olympiad 21 January part-1...

Class 8 Maths Olympiad 21 January part-1 | Maths Olympiad full solution PSEB | GAURAV CROOKS #pseb

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In equalitative analysis, cations of graph II as well as group IV both are precipitated in the form of sulphides. Due to low value of K_(sp) of group II sulphides, group reagent is H_(2)S in the presence of dil. HC1 , and due to high value of K_(sp) of group IV sulphides, group reagent is H_(2)S in the presence of NH_(4)OH and NH_(4)C1 . In a solution containing 0.1M each of Sn^(2+), Cd^(2+) , and Ni^(2+) ions, H_(2)S gas is passed. K_(sp) of SnS = 8 xx 10^(-29), K_(sp) of CdS = 10^(-28), K_(sp) of NiS - 3 xx 10^(-21) K_(1) of H_(2)S = 1 xx 10^(-7), K_(2) of H_(2)S = 1 xx 10^(-14) If 0.1M HC1 is mixed in the solution containing only 0.1 M Cd^(2+) ions and saturated with H_(2)S , then [Cd^(2+)] remaining in the solution after CdS stopes to precipitate is: