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When electricity is passed through calci...

When electricity is passed through calcium nitrate solution in water, ______ is formed at the cathode because it requires ________ electrical energy to get discharged.

A

Hydrogen, more

B

Calcium more

C

Hydrogen, less

D

Calcium, less

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the electrolysis of calcium nitrate solution (Ca(NO3)2) and determine what is formed at the cathode and the energy requirements for that reaction. ### Step-by-Step Solution: 1. **Identify the Components in the Solution**: - Calcium nitrate dissociates in water to form calcium ions (Ca²⁺) and nitrate ions (NO3⁻). - The solution also contains water, which can dissociate into hydrogen ions (H⁺) and hydroxide ions (OH⁻). 2. **Determine the Reactions at the Electrodes**: - At the cathode (negative electrode), reduction occurs. This means that cations (positively charged ions) will be attracted to the cathode. - The two main cations present are Ca²⁺ and H⁺ from water. 3. **Evaluate the Discharge of Ions**: - The discharge of ions at the cathode depends on their standard electrode potentials. - Calcium ions (Ca²⁺) can be reduced to calcium metal (Ca), but this reaction requires a higher amount of electrical energy. - Hydrogen ions (H⁺) can be reduced to form hydrogen gas (H₂), which requires less electrical energy. 4. **Identify the Product at the Cathode**: - Since hydrogen ions require less energy to be discharged compared to calcium ions, hydrogen gas (H₂) will be formed at the cathode. 5. **Complete the Sentence**: - Therefore, when electricity is passed through calcium nitrate solution in water, **hydrogen gas** is formed at the cathode because it requires **less** electrical energy to get discharged. ### Final Answer: When electricity is passed through calcium nitrate solution in water, **hydrogen gas** is formed at the cathode because it requires **less** electrical energy to get discharged.
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