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The van der Waal's equation for 0.5 mole...

The van der Waal's equation for 0.5 mole of gas is :
1) `(P+a/(4V^2))((V-b)/2)=(2RT)/2`
2)1) `(P+a/(4V^2))(2V-b)=RT`
3)1) `(P+a/(4V^2))(2V-4b)=RT`
4)1) `(P+a/(4V^2))=(2RT)/(2(V-b))`

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