Anti Markonikoves Rules

Assertion : Propene reacts with HBr in the presence of peroxides to give 1-bromopropane. Reason : Alkenes react with HBr in the presence of peroxides according to anti Markovnikov's rule.

Free Radicals Addition || Kolbe Electrolysis || Anti MarkownikOFf Rule

Haloalkanes Haloarenes|Preparation Of Haloalkanes|Markonikove's Rule|Preparation Of Haloalkanes|OMR

In which case the product formed is in accordance of anti Markownikoff's rule?

In the presence of peroxide addition of HBr to propene takes place according to anti Markownikoff's rule but peroxide effect is not seen in the case of HCl and HI. Explain.

The addition of HCl in the presence of peroxide does not follow anti-Markownikoff's rule because