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The ratio of the frequencies of the long...

The ratio of the frequencies of the long wavelenght limits of Lyman and Balmer series of hydrogen spectrum is

A

`27:5`

B

`5:27`

C

`4:1`

D

`1:4`

Text Solution

Verified by Experts

The correct Answer is:
A

For Lyman series, `n_(1)= 1, n_(2)=2`
`(1)/((lamda_("max"))_(1))= f_(1)= Rc [(1)/(1^(2))- (1)/(2^(2))]= (3Rc)/(4)`
For Balmer series,
`n_(1)= 2, n_(3)= 3`
`(1)/((lamda_("max"))_(2))= f_(2) = Rc [(1)/(2^(2))- (1)/(3^(2))] =(5Rc)/(36)`
`(f_(1))/(f_(2))= (3Rc)/(4) xx (36)/(5Rc) = (27)/(5)`
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