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WERNER COORDINATION THEORY

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WERNER’S THEORY OF COORDINATION COMPOUNDS

LIMITATIONS OF BOHR THEORY AND BOHR-SOMMERFELD'S ATOMIC THEORY

According to werner, the arrangement of 6 groups around the metal centre within the co-ordination sphere can lead to three possible geometries (For Q. 1 and Q. 2) : planar hexagon, trigonal prism and octahedral. For a particular geometry, if the groups (i.e. ligands) are arranged in different ways then the possibility of geometrical isomerism will arise. A complex [PtCl_(2)(NH_(3))_(4)]^(2+) in WERNER 'S universe has a total 3 stereo-isomers possible. If Werner was present, then, according to him, what can be the probable shape of the complex ?

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