Home
Class 11
CHEMISTRY
When 400 ml of 2.0 N solution of a weak ...

When 400 ml of 2.0 N solution of a weak acid is neutralized by a dilute aqueous solution of sodium hydroxide under standard conditions, 4.4 kJ amount of heat is liberated. Therefore, the standard enthalpy of neutralization of this weak acid in kJ `eq^(-1)` is

A

`-11`

B

`-44`

C

`-55`

D

`-22`

Text Solution

Verified by Experts

The correct Answer is:
C

No. of equivalents of weak acid 0.4 `xx` 0.2 = 0.08 So, amount of heat liberated per equivalent `= (4.4)/(0.08) = -55` kJ
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS AND THERMOCHEMISTRY

    ERRORLESS|Exercise NCERT Based Questions (Bond Energy)|15 Videos
  • THERMODYNAMICS AND THERMOCHEMISTRY

    ERRORLESS|Exercise NCERT Based Questions (Free Energy and Work Function) |37 Videos
  • THERMODYNAMICS AND THERMOCHEMISTRY

    ERRORLESS|Exercise NCERT Based Questions (IInd & IIIrd Law of Thermodynamics and Entropy)|41 Videos
  • THE S-BLOCK ELEMENTS

    ERRORLESS|Exercise Assertion & Reason|10 Videos

Similar Questions

Explore conceptually related problems

pH of 0.05 aqueous solution of weak acid HA (K_a=4×10^(-4)) is

Enthalpy of neutralzation is defined as the enthalpy change when 1 mole of acid / / base is completely neutralized by base // acid in dilute solution . For Strong acid and strong base neutralization net chemical change is H^(+) (aq)+OH^(-)(aq)to H_(2)O(l) Delta_(r)H^(@)=-55.84KJ//mol DeltaH_("ionization")^(@) of aqueous solution of strong acid and strong base is zero . when a dilute solution of weak acid or base is neutralized, the enthalpy of neutralization is somewhat less because of the absorption of heat in the ionzation of the because of the absorotion of heat in the ionization of the weak acid or base ,for weak acid /base DeltaH_("neutrlzation")^(@)=DeltaH_("ionization")^(@)+ Delta _(r)H^(@)(H^(+)+OH^(-)to H_(2)O) If enthalpy of neutralization of CH_(3)COOH by NaOH is -49.86KJ // mol then enthalpy of ionization of CH_(3)COOH is:

Enthalpy of neutralzation is defined as the enthalpy change when 1 mole of acid /base is completely neutralized by base // acid in dilute solution . For Strong acid and strong base neutralization net chemical change is H^(+) (aq)+OH^(-)(aq)to H_(2)O(l) Delta_(r)H^(@)=-55.84KJ//mol DeltaH_("ionization")^(@) of aqueous solution of strong acid and strong base is zero . when a dilute solution of weak acid or base is neutralized, the enthalpy of neutralization is somewhat less because of the absorption of heat in the ionzation of the because of the absorotion of heat in the ionization of the weak acid or base ,for weak acid /base DeltaH_("neutrlzation")^(@)=DeltaH_("ionization")^(@)+ Delta _(r)H^(@)(H^(+)+OH^(-)to H_(2)O) What is DeltaH^(@) for complate neutralization of strong diacidic base A(OH)_(2)by HNO_(3) ?

ERRORLESS-THERMODYNAMICS AND THERMOCHEMISTRY-NCERT Based Questions (Heat of Reaction)
  1. The standard heats of formation of CH(4), H(2)O and CH(3)OH are -76, ...

    Text Solution

    |

  2. The enthalpy of formation of methane C(( S))+2H(2(g)) rarr CH4(g) at ...

    Text Solution

    |

  3. When 400 ml of 2.0 N solution of a weak acid is neutralized by a dilut...

    Text Solution

    |

  4. The values of heat of combustion of ethane (C(2)H(6)) and ethyne (C(2)...

    Text Solution

    |

  5. In which of the following reactions, the heat liberated is known as ''...

    Text Solution

    |

  6. What would be the heat released when an aqueous solution containing 0....

    Text Solution

    |

  7. A cylinder of gas is assumed to contain 11.6 kg of butane (C4H10). If ...

    Text Solution

    |

  8. Compounds with high heat of formation are less stable because

    Text Solution

    |

  9. Which of the following reactions is not exothermic

    Text Solution

    |

  10. The heat of combustion of carbon to CO(2) is -393.5 kJ/mol. The heat r...

    Text Solution

    |

  11. If (i) C+ O(2) rarr CO(2), (ii) C +1//2O(2) rarr CO, (iii) CO+ 1//2O(2...

    Text Solution

    |

  12. Given: i. 2Fe(s) +(3)/(2)O(2)(g) rarr Fe(2)O(3)(s), DeltaH^(Theta) =...

    Text Solution

    |

  13. If 27 g of water is formed during complete combustion of pure propene ...

    Text Solution

    |

  14. Which of the following equations corresponds to the definition of enth...

    Text Solution

    |

  15. Heat of neutralization of strong acid against strong base is constant ...

    Text Solution

    |

  16. The enthalpies of formation of Al(2)O(3) and Cr(2)O(3) are -1596KJ and...

    Text Solution

    |

  17. Sodium chloride is soluble in water but not in benzene because

    Text Solution

    |

  18. One mole of NaCl((s)) on melting absorbed 30.5 kJ of heat and its entr...

    Text Solution

    |

  19. During complete combustion of one mole of butane ,2658Kj of heat is...

    Text Solution

    |

  20. delta(f) U^(Ө) "of formation of" CH(4)(g) at a certain temperature is ...

    Text Solution

    |