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If in the reaction N2O4 hArr 2NO(2),alph...

If in the reaction `N_2O_4 hArr 2NO_(2),alpha` is that part of `N_2O_4` which dissociates, then the number of moles at equilibrium will be

A

3

B

1

C

`(1- alpha)^2`

D

`(1+ alpha)`

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the equilibrium of the reaction: \[ N_2O_4 \rightleftharpoons 2NO_2 \] Let's denote the initial number of moles of \( N_2O_4 \) as \( 1 \) mole (for simplicity). The variable \( \alpha \) represents the fraction of \( N_2O_4 \) that dissociates at equilibrium. ### Step-by-Step Solution: 1. **Initial Moles**: - At the start (T = 0), we have: - Moles of \( N_2O_4 \) = 1 - Moles of \( NO_2 \) = 0 2. **Change in Moles**: - When \( \alpha \) moles of \( N_2O_4 \) dissociate, the changes in the moles will be: - Moles of \( N_2O_4 \) that dissociate = \( \alpha \) - Moles of \( NO_2 \) produced = \( 2\alpha \) (since 1 mole of \( N_2O_4 \) produces 2 moles of \( NO_2 \)) 3. **Moles at Equilibrium**: - At equilibrium, the moles will be: - Moles of \( N_2O_4 \) = \( 1 - \alpha \) - Moles of \( NO_2 \) = \( 2\alpha \) 4. **Total Moles at Equilibrium**: - To find the total number of moles at equilibrium, we add the moles of both species: \[ \text{Total moles} = \text{Moles of } N_2O_4 + \text{Moles of } NO_2 \] \[ \text{Total moles} = (1 - \alpha) + (2\alpha) = 1 + \alpha \] 5. **Final Answer**: - Therefore, the total number of moles at equilibrium is \( 1 + \alpha \).

To solve the problem, we need to analyze the equilibrium of the reaction: \[ N_2O_4 \rightleftharpoons 2NO_2 \] Let's denote the initial number of moles of \( N_2O_4 \) as \( 1 \) mole (for simplicity). The variable \( \alpha \) represents the fraction of \( N_2O_4 \) that dissociates at equilibrium. ### Step-by-Step Solution: ...
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