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Te defect that is more likely to occur i...

Te defect that is more likely to occur in almost all types of ionic crystals is

A

Non-stoichiometric defects

B

Schottky defect

C

Frenkel defect

D

All the above

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The correct Answer is:
B

Schottky defect is shown by highly ionic compounds, e.g. NaCl,KCl,KBr, AgBr,CsCl etc.
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Examine the given defective crystal {:(A^(+), B^(-),A^(+),B^(-),A^(+)),(B^(-), O,B^(-), A^(+),B^(-)),(A^(+),B^(-),A^(+),O,A^(+)),(B^(-),A^(+),B^(-),A^(+),B^(-)):} Answer the following question : (i) What type of stoichiometric defect is shown by the crystal ? (ii) How is the density of the crystal affected by this defect ? (iii) What type of ionic substances show such defect ?

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions. When an ion leaves ir correct lattice and occupies interstital sites in its crystal lattice, it is called

ERRORLESS-SOLID STATE-NCERT BASED QUESTIONS (DEFECTS IN CRYSTAL)
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  3. Schottky defect occurs mainly in electrovalent compounds where

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  4. Zine oxide is white but it turns yellow on heating . Explain.

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  5. Frenkel defect generally appears in

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  6. The following is not a function of an impurity present in a crystal:

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  7. Point defects are present in .

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  8. If a non-metal is added to the interstitial sites of a metal, then the...

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  9. In AgBr crystal , the ion size lies in the order Ag^(+) lt lt Br^(-) T...

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  10. Which one of the following is the most correct statement?

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  11. The flame colours of metal ions are due to

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  12. Which one of the following crystal does not exhibit Frenkel defect?

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  13. Which of the following defect is seen in FeO

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  14. To get a n- type semiconductor from silicon , it should be doped...

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  15. which kind of defects are introduced by doping ?

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  16. silicon doped with electron rich impurity forms ………. .

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  17. Pure silicon dopend with phosphorus is a

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  19. Schottky defect in a crystal arises due to

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  20. The wrong statement about the interstitial compound is

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