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In aqueous solution Cr^(2+) is stronger ...

In aqueous solution `Cr^(2+)` is stronger reducing agent than `Fe^(2+)`. This is because

A

`Cr(2+)`ion is more stable than `Fe^(2+)`

B

`Cr^(3+)` ion with `d^3` configuration has favourable crystal field stabilisation energy

C

`Cr^(3+)` has half-filled configuration and hence more stable

D

`Fe^(3+)` in aqueous solution is more stable than`Cr^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
B


Half – filled `(t_(2g)^3)` configuration has favourable crystal field stabilizing energy. So `Cr^(2+)` can readily form `Cr^(3+)`, being a strong reducting agent.
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