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Why Mn^(2+) compounds are more stable th...

Why `Mn^(2+)` compounds are more stable than `Fe^(2+)` compounds towards oxidation to their + 3 state ?

A

`Mn^(2+)` is more stable with high 3rd ionisation energy

B

`Mn^(2+)` is bigger in size

C

`Mn^(2+)` has completely filled d-orbitals

D

`Mn^(2+)` does not exist

Text Solution

Verified by Experts

The correct Answer is:
A

`Mn^(2+)` has stable half-filled electronic configuration thus, it has high third ionisation energy while `Fe^(2+)` on losing one more electron will acquire this stable electronic configuration. Thus, `Fe^(2+)` is more prone to get oxidised to +3 oxidation state.
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ERRORLESS-THE d-AND f- BLOCK ELEMENTS -NCERT BASED QUESTIONS (Compounds of Transitional Elements)
  1. The correct order of increasing oxidising power in the series is

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  2. The correct formula of permaganic acid is

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  3. Why Mn^(2+) compounds are more stable than Fe^(2+) compounds towards o...

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  4. Potassium permanganate acts as an oxidant in neutral, alkaline as well...

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  5. Which of the oxide of manganese is amohoteric

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  6. MnO(4)^(-) reacts with Br^(-) in alkaline pH to give

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  7. Which of the following statement is incorrect for KMnO4

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  8. Mn^(2+) can be converted into Mn^(7+) by reacting with

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  9. Formula of thiosulphate, manganate and arsenate respectively are

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  10. The number of moles of KMnO(4) that will be needed to react completely...

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  11. When a brown compound of Mn (A) is teated with HCl, it gives a gas (B)...

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  12. On addition of small amoung of KMnO(4) to concentrated H(2)SO(4), a gr...

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  13. When KMnO(4) solution is added to oxalic acid solution , the decolouri...

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  14. KMnO(4) acts as an oxidising agent in acidic medium. The number of mol...

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  15. KMnO(4) acts as an oxidising agent in alkaline medium when alkaline KM...

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  16. Why HCl not used to make the mdeium acidic in oxidation reactions of K...

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  17. Reaction of solid KMnO4 which conc. H2SO4 produces manganese heptoxide...

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  18. Higher oxidation state of manganese in fluoride is +4 (MnF(4)) but hig...

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  19. Invar, an alloy of Fe and Ni is used in watches and meter scale, its c...

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  20. The percentage of carbon in cost iron is :

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