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The five d-orbitals are designated as d(...

The five d-orbitals are designated as `d_(xy), d_(yz), d_(xz), d_(x^(2) - y^(2))` and `d_(z^(2))` . Choose the correct statement.

A

The shapes of the first three orbitals are similar but that of the fourth and fifth orbitals are different

B

The shapes of all five d-orbitals are similar

C

The shapes of the first four orbitals are similar but that of the fifth orbital is different

D

The shapes of all five d-orbitals are different

Text Solution

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The correct Answer is:
C

First four orbitals contain four lobes, while fifth orbital consists of only two lobes. The lobes of `d_(xy)` orbital lie between x and y axis. Similar is the case for `d_(yz)andd_(zx)` Four lobes of `d_(x^(2)-y^(2))` orbital are lying along x and y axis while two lobes of `d_(z^(2))` orbital are lying along z-axis.
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When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. In sp^(3)d^(2) hybridisation, which sets of d-orbitals is involved ?

When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. Molecule having trigonal bipyramidal geometry and sp^(3) d hybridisation, d-orbitals involved is :

ERRORLESS-STRUCTURE OF ATOM-NCERT BASED QUESTIONS (Quantum Number, Electronic Configuration and Shape of Orbitals)
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  4. The number of radial nodes for 3p orbital is......

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  5. Number of angular nodes for 4d orbtial is.........

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  6. Total number of orbitals associated with thrid shell will be.....

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  7. Orbital angular momentum depends on .........

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  8. For the electrons of oxygen atom, which of the following statemetns c...

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  9. The five d-orbitals are designated as d(xy), d(yz), d(xz), d(x^(2) - y...

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  10. Arrabge in decreasing order, the energy of 2s orbital in the following...

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  11. A filled or half-filled set of p or d -orbitals is spherically symmetr...

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  12. Which of the following orbitals will have zero probability of finding ...

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  13. The probability density plots of 1 s and 2s orbitals are given in figu...

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  14. The set of principal (n), azimuthal (l) and magnetic (m(l)) quantum nu...

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  15. The number of valence electrons in an atom with electronic configurati...

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  16. Maximum number of electrons that can be accommodated in the subshell w...

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  17. The element which readily forms an ionic bond has the electronic...

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  18. The eleectronic cofiguration which obeys Hund's rule for the ground s...

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  19. The maximum number of electrons that can be filled in the shell with ...

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