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In diborane, the H-B-H bond angle is 120...

In diborane, the H-B-H bond angle is `120^(@)`. The hybridization of borons is likely to be

A

`sp`

B

`sp^2`

C

`sp^3 `

D

`dsp^2`

Text Solution

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The correct Answer is:
C

Each .B. atom in diborane `(B_2H_6)` is `sp^3` - hybridized of the four hybrid orbitals, three have one electron each, while the fourth is empty. Two orbitals of each B from `sigma` - bonds with two H–atoms, while one of the remaining hybrid orbitals (either filled or empty), 1s orbital of H–atom and one of the hybrid orbitals of other B atom overlap to form three centred two electron bond. So there exists two such type of three centred bond.
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