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Which of the following statements is cor...

Which of the following statements is correct

A

`SF_4` is polar and non-reactive

B

`SF_6` is non-polar and very-reactive

C

` SF_6` is a strong fluorinating agent

D

`SF_4` is prepared by fluorinating `SCl_2` with NaF

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements regarding SF4 and SF6 is correct, we can analyze each statement step by step. ### Step 1: Analyze the first statement **Statement:** SF4 is polar and non-reactive. - **Analysis:** - SF4 (sulfur tetrafluoride) has a seesaw molecular geometry due to the presence of one lone pair on the sulfur atom. This geometry leads to an uneven distribution of charge, making SF4 a polar molecule. - However, the statement claims that SF4 is non-reactive, which is incorrect. SF4 is indeed reactive due to the presence of the highly electronegative fluorine atoms and can participate in various chemical reactions. **Conclusion:** This statement is incorrect. ### Step 2: Analyze the second statement **Statement:** SF6 is non-polar and very reactive because of steric hindrance. - **Analysis:** - SF6 (sulfur hexafluoride) has an octahedral geometry, which results in a symmetrical distribution of charge. Therefore, SF6 is a non-polar molecule. - The claim that SF6 is "very reactive because of steric hindrance" is misleading. SF6 is actually quite stable and is not very reactive; it is known to be a strong fluorinating agent due to the presence of fluorine atoms, but steric hindrance is not the reason for its reactivity. **Conclusion:** This statement is incorrect. ### Step 3: Analyze the third statement **Statement:** SF6 is a strong fluorinating agent. - **Analysis:** - SF6 is indeed a strong fluorinating agent. Its stability and the presence of highly electronegative fluorine atoms allow it to effectively transfer fluorine in reactions, making it useful in various chemical processes. **Conclusion:** This statement is correct. ### Step 4: Analyze the fourth statement **Statement:** SF4 is prepared by fluorinating SCl2 with NaF. - **Analysis:** - The preparation of SF4 involves the reaction of sulfur dichloride (SCl2) with sodium fluoride (NaF). The balanced reaction is: \[ \text{SCl}_2 + 2 \text{NaF} \rightarrow \text{SF}_4 + 2 \text{NaCl} \] - This indicates that SF4 can indeed be synthesized using SCl2 and NaF. **Conclusion:** This statement is also correct. ### Final Conclusion - The correct statements are: - SF6 is a strong fluorinating agent. - SF4 is prepared by fluorinating SCl2 with NaF. ### Summary of Correct Statements: 1. SF6 is a strong fluorinating agent. 2. SF4 is prepared by fluorinating SCl2 with NaF.

To determine which of the statements regarding SF4 and SF6 is correct, we can analyze each statement step by step. ### Step 1: Analyze the first statement **Statement:** SF4 is polar and non-reactive. - **Analysis:** - SF4 (sulfur tetrafluoride) has a seesaw molecular geometry due to the presence of one lone pair on the sulfur atom. This geometry leads to an uneven distribution of charge, making SF4 a polar molecule. - However, the statement claims that SF4 is non-reactive, which is incorrect. SF4 is indeed reactive due to the presence of the highly electronegative fluorine atoms and can participate in various chemical reactions. ...
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