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The correct geometry and hybridization f...

The correct geometry and hybridization for `XeF_4` are

A

Square planar, `sp^3 d^2`

B

Octahedral, `sp^3 d^2`

C

Trigonal bipyramidal, `sp^3 d`

D

Planar triangle, `sp^3 d^3`

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The correct Answer is:
To determine the correct geometry and hybridization for \(XeF_4\), we can follow these steps: ### Step 1: Determine the Valence Electrons - Xenon (Xe) is in Group 18 of the periodic table and has 8 valence electrons. - Each fluorine (F) atom has 7 valence electrons, and since there are 4 fluorine atoms, they contribute \(4 \times 7 = 28\) valence electrons. - However, we only need to consider the valence electrons of xenon for hybridization and geometry. **Hint:** Count the valence electrons of the central atom (Xe) and the surrounding atoms (F) to understand the bonding situation. ### Step 2: Bonding and Lone Pairs - In \(XeF_4\), xenon forms 4 bonds with the 4 fluorine atoms. - This uses up 4 of the 8 valence electrons from xenon. - The remaining 4 valence electrons will form 2 lone pairs on the xenon atom. **Hint:** Remember that each bond uses 2 electrons, and lone pairs are the remaining electrons after bonding. ### Step 3: Calculate the Steric Number - The steric number is calculated by adding the number of sigma bonds and lone pairs on the central atom. - In \(XeF_4\), there are 4 sigma bonds (one for each \(Xe-F\) bond) and 2 lone pairs. - Therefore, the steric number is \(4 + 2 = 6\). **Hint:** The steric number helps determine the hybridization and geometry of the molecule. ### Step 4: Determine Hybridization - A steric number of 6 corresponds to \(sp^3d^2\) hybridization. - This involves the mixing of one s orbital, three p orbitals, and two d orbitals. **Hint:** Hybridization can be deduced from the steric number, where each number corresponds to a specific type of hybridization. ### Step 5: Determine the Geometry - The geometry associated with \(sp^3d^2\) hybridization is octahedral. - However, due to the presence of lone pairs, the actual shape of the molecule is square planar. **Hint:** While hybridization gives the geometry, the presence of lone pairs can alter the molecular shape. ### Final Answer - The correct geometry of \(XeF_4\) is square planar, and the hybridization is \(sp^3d^2\). ### Summary - **Hybridization:** \(sp^3d^2\) - **Geometry:** Square planar (with an underlying octahedral arrangement due to hybridization).

To determine the correct geometry and hybridization for \(XeF_4\), we can follow these steps: ### Step 1: Determine the Valence Electrons - Xenon (Xe) is in Group 18 of the periodic table and has 8 valence electrons. - Each fluorine (F) atom has 7 valence electrons, and since there are 4 fluorine atoms, they contribute \(4 \times 7 = 28\) valence electrons. - However, we only need to consider the valence electrons of xenon for hybridization and geometry. **Hint:** Count the valence electrons of the central atom (Xe) and the surrounding atoms (F) to understand the bonding situation. ...
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Hybridization & Molecular Geometry

ERRORLESS-CHEMICAL BONDING AND MOLECULAR STRUCTURE-PAST YEARS QUESTIONS
  1. XeF2 is isostructural with

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  2. Which one of the following species has plane triangular shape ?

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  3. The correct geometry and hybridization for XeF4 are

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  4. Which of the following statement is not correct

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  5. Which among the following possesses an sp hybridized carbon in its str...

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  6. In which of the following pairs, both the species are not isostructura...

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  7. The structural formula of a compound is CH(3)-CH=C=CH(2). The type of ...

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  8. Out of SO2, BeCl2, O3, H2O and HgCl2, the linear species are

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  9. The smallest bond angle around the central atom will be there in

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  10. Match the compounds given in Column I with the hybridisation and shape...

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  11. In an octahedral structure , the pair of d orbitals involved in d^(2)...

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  12. Planar structure is shown by

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  13. Which of the following molecules represents the order of hybridisation...

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  14. The outer orbitals of C in ethene molecule can be considered to be hyb...

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  15. Which one of the following molecules contains no pi bond?

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  16. Which of the following species contains equal number of pi and pi bond...

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  17. Among the following which one is wrong statement ?

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  18. Which molecules has zero dipole moment ?

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  19. Which bond angle, theta would result in the maximum dipole moment for...

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  20. H2O is dipolar, whereas BeF2 is not. It is because

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