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Which one of the following is non-ideal ...

Which one of the following is non-ideal solution?

A

Benzene + toluene

B

n -hexane + n -heptane

C

Ethyl bromide + ethyl iodide

D

`C Cl_(4)+CHCl_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D
Mixing of `C Cl_(4)` (non–polar) and `CHCl_(3)` (polar) is an endothermic process `(DeltaH_(mix)gt0)`.
Weak vander waal forces are formed between the molecules so vapour pressure of the solution is greater than expected from Raoult’s law.
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