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Reaction : - 3ClO^(-) to ClO3^(-) +2Cl...

Reaction : - `3ClO^(-) to ClO_3^(-) +2Cl^(-) ` occurs in following two steps
`(i) 2ClO^(-) rightarrow ClO_(2)^(-) +Cl^(-) ` ( slow step )
`(ii) ClO_(2) ^(-) +ClO^(-) overset(K_(2)) to ClO_(3)^(-) +Cl^(-) ` ( fast step)
then the rate of given reaction - ______.

A

`K_(1)[ClO^(-)]^(2)`

B

`K_(1)[ClO^(-)]`

C

`K_(2)[ClO_(2)^(-)][ClO^(-)]`

D

`K_(1)[ClO^(-)]^(3)`

Text Solution

Verified by Experts

The correct Answer is:
A

Slowest step is the rate determining step . Hence `"Rate"=K_(1)[ClO^(-)]^(2)`
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