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For a first order reaction, the time req...

For a first order reaction, the time required for `99.9%` of the reaction to take place is nearly

A

`10` times that required for half of the reaction

B

`100` times that required for two-third of the reaction

C

`10` times that required for one-fourth of the reaction

D

`20` times that required for half of the reaction

Text Solution

Verified by Experts

The correct Answer is:
A

Time required to complete `99.9%` of reaction
`t_(99.9)=(2.303)/(k)log.(100)/(100-99.9)`
= `(2.303)/(k)log1000.=(6.909)/(k)`
and `t_(1//2)=(2.303)/(k)log.(100)/(100-50)`
= `(2.303)/(k)log2.=(0.693)/(k)`
So, `t_(99.9)` is 10 times that of required for half of the reaction .
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