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Due to the presence of ambidenate ligand...

Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type `[Pd(C_(6)H_(5))_(2)(SCN)_(2)]` & `[Pd(C_(6)H_(5))_(2)(NCS)_(2)]` are

A

Linkage isomers

B

Coordination isomers

C

Ionisation isomers

D

Geometrical isomers

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The correct Answer is:
A
Linkage isomers
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Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] & [Pd(C_(6H_(5))_(2)(NCS)_(2)] are

Read the passage given below and answer the following questions : The existence of coordination compounds with the same formula but different arragements of the ligands was crucial in the development of coordination chemistry. Two or more compounds with the same formula but different arrangements of the atoms are called isomers. Isomers are compounds with the same molecular formula but different structural formulas and do not necessarily share similar properties. There are many different classes of isomers, like stereoisomers, enantiomers, and geometrical isomers. There are two main forms of isomerism: structural isomerism and stereoisomerism. The different chemical formulas in structural isomers are caused either by a difference in what ligands are bonded to the central atoms or how the individual ligands are bonded to the central atoms. The following questions are multiple choice questions. Choose the most appropriate answer: Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] are

[Pd(NH_(3))_(2)(SCN)_(2)] and [Pd(NH_(3))_(2)(NCS)_(2)] are :

Type of isomerism which exists between [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] is :

The following isomers refer to [{(C_(6)H_(5))_"(3)"P}_(2)Pd(SCN)_(2)] and [{(C_(6)H_(5))_(3)P}_(3)Pd(NCS)_(2)]

Type of isomerism which exists between [Pd( C_6H_5)_2 (SCN)_2] and [Pd(C_6H_5)_2(NCS)_2] is

ERRORLESS-COORDINATION COMPOUNDS-NCERT BASED QUESTION (NOMENCLATURE, OXIDATION STATE)
  1. Which of the following compounds shows optical isomerism?

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  2. Indicate the complex ion which shows geometrical isomerism :

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  3. Due to the presence of ambidenate ligands coordination compounds show ...

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  4. [Co(NH3)5Br]SO4 and [Co(NH3)5SO4]Br are the examples of:

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  5. What kind of isomerism exists between [Cr(H2O)6]Cl3, (violet) and [Cr(...

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  6. Which one of the following will not show geometrical isomerism?

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  7. Draw isomers of the complex ion [Co(en)(2)Cl(2)]^(+)

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  8. The number of isomers possible for square planar complex K2[PdClBr2SCN...

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  9. Number of possible isomers for the complex [Co(en)(2)CI(2)]  will be (...

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  10. In coordination compound [Co(en)(2)Cl(2)]Cl which is false

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  11. Which of the following complex does not show geometrical isomerism

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  12. Both geometrical and optical isomerism are exhibited by

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  13. For the given complex [CoCl(2)(en)(NH(3))(2)]^(+), the number of geome...

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  14. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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  15. The optically active co-ordination complex ion among the following is

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  16. Which of the following has an optical isomer? (en=ethylenediamine) ?

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  17. Which among the following statement are true for the complex [Co(NH(...

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  18. The isomer is

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  19. The number of geometical isomers possible for a square planar complex ...

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  20. The total number possible isomers for the complex compound [Cu^(II)(NH...

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