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Which of the following statements is inc...

Which of the following statements is incorrect

A

In `K_3 [Fe(CN)_6]` , the ligand has satisfied only the secondary valencies of ferric ion

B

In `K_3 [Fe(CN)_6]` , the ligand has satisfied both primary and secondary valencies of ferric ion

C

In `K_4 [Fe(CN)_6]` , the ligand has satisfied both primary and secondary valencies of ferric ion

D

In `[Cu(NH_3)_4]SO_4` , the ligand has satisfied only the secondary valencies of copper

Text Solution

Verified by Experts

The correct Answer is:
A

In `K_3 [Fe(CN)_6]` the ligand are negative which is present in coordination spheres shows a dual behaviour. It may satisfy both primary & secondary valencies while neutral ligand satisfies only secondary valencies.
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