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π-bonding is not present in...

π-bonding is not present in

A

Grignard reagent/Tetramethyl lead

B

Dibenzene chromium

C

Zeise’s salt

D

Ferrocene

Text Solution

AI Generated Solution

The correct Answer is:
To determine where π-bonding is not present, we need to analyze the given options based on the nature of bonding in coordination compounds and organic molecules. Here is a step-by-step solution: ### Step 1: Understand π-bonding - π-bonding occurs when two lobes of an orbital on one atom overlap with two lobes of an orbital on another atom, forming a bond. This typically happens in double and triple bonds, as well as in certain coordination compounds. ### Step 2: Identify the options - The question asks for a compound or coordination complex where π-bonding is absent. We need to evaluate each option to see if it contains π-bonds. ### Step 3: Analyze the given examples 1. **Dibenzene (C6H4)**: This compound has a cyclic structure with alternating double bonds, which means it has π-bonding. 2. **Tetramethyl lead (Pb(CH3)4)**: This compound consists of lead bonded to four methyl groups. There are no double bonds present, indicating that there is no π-bonding. 3. **RNGX (where R is an alkyl group and X is a halogen)**: This is a general representation of alkyl halides, which typically do not have π-bonds unless there are double bonds in the alkyl group. 4. **Cyclopentadiene**: This compound has a cyclic structure with two double bonds, indicating the presence of π-bonding. ### Step 4: Conclusion - Based on the analysis, **tetramethyl lead (Pb(CH3)4)** is the compound where π-bonding is not present. ### Final Answer - The correct answer is **tetramethyl lead (Pb(CH3)4)**. ---

To determine where π-bonding is not present, we need to analyze the given options based on the nature of bonding in coordination compounds and organic molecules. Here is a step-by-step solution: ### Step 1: Understand π-bonding - π-bonding occurs when two lobes of an orbital on one atom overlap with two lobes of an orbital on another atom, forming a bond. This typically happens in double and triple bonds, as well as in certain coordination compounds. ### Step 2: Identify the options - The question asks for a compound or coordination complex where π-bonding is absent. We need to evaluate each option to see if it contains π-bonds. ...
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