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The correct order of the stoichiometries...

The correct order of the stoichiometries of `AgCl` formed when `AgNO_3` in excess is treated with the complexes: `CoCl_(3).6NH_3, CoCl_(3).5NH_3, CoCl_(3). 4NH_3` respectively is:

A

1 AgCl, 3AgCl, 2AgCl

B

3 AgCl, AgCl, 2AgCl

C

3 AgCl, 2AgCl, 1AgCl

D

2AgCl, AgCl, 1AgCl

Text Solution

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The correct Answer is:
C

3 AgCl, 2AgCl, 1AgCl
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The correct order of stoichiometries of AgCI formed when AgNO_(3) in excess is treated with the complex: CoCI_(3) . 6NH_(3), CoCI_(3) . 5 NH_(3), CoCI_(3) . 4NH_(3) respectively is:

In the complex CoCl_(3).4NH_(3)

In the compound CoCl_(3).5NH_(3) :

IUPAC name of the complex CoCl_(3) 5NH_(3) is

The complex CoCl_(3),3NH_(3) ionizes to give

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