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Toluene react with a halogen in the pres...

Toluene react with a halogen in the presence of iron (III) chloride giving ortho andpara halo compounds. The reactions is

A

Electrophilic elimination reaction

B

Electrophilic substitution reaction

C

Free radical addition reaction

D

Nucleophilic substitution reaction

Text Solution

Verified by Experts

The correct Answer is:
B

Toluene reacts with a halogen in the presence of iron (III) chloride giving ortho and para halo compounds. The reaction is electrophilic substitution reaction
It has the following mechanism
`Cl-Cl overset(FeCl_3)(rarr)FeCl_4^(-)+Cl^(+)`

In this mechanism, electrophile `Cl^(+)` attacks to electron rich benzene ring and replaces hydrogen. So, the reaction is electrophilic substitution reaction.
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