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Cholorobenzene is formed by reaction of ...

Cholorobenzene is formed by reaction of chlorine with benzene in the presence of `AlCl_(3)`. Which of the following species attacks the benzene ring in this reaction?

A

`Cl^(-)`

B

`Cl^(+)`

C

`AlCl_3`

D

`[AlCl_4]^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B

In this reaction, `AlCl_3` is a catalyst which activate the chlorine molecule to show heterolytic cleavage. `AlCl_3` is electron deficient molecule and form `AlCl^(-)""_4` and `Cl^(+)` when reacts with `Cl_2` . This `Cl^(+)` electrophile attacks on electron rich benzene ring.
`AlCl_3+Cl_2 rarr [AlCl_4]^(-)+Cl^(+)`
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