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When ethyl alcohol (C(2)H(5)OH) reacts w...

When ethyl alcohol `(C_(2)H_(5)OH)` reacts with thionyl chloride, in the presence of pyridine, the product obtained is

A

`CH_3CH_2Cl+HCl`

B

`C_2H_5Cl+HCl+SO_2`

C

`CH_3CH_2Cl+H_2O+SO_2`

D

`CH_3COCl+HCl+SO_2`

Text Solution

Verified by Experts

The correct Answer is:
B
Darzen’s process :
`CH_3CH_2OH+SOCl_2 overset("Pyridine")(rarr)CH_3CH_2Cl+SO_2`
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Knowledge Check

  • When ehtyl alcohol ( C_(2)H_(5)OH ) reacts with thionyl chloride, in the presence of pyridine , the product obtained is ________.

    A
    `CH_(3)CH_(2)Cl+HCl`
    B
    `C_(2)H_(5)Cl+HCl+SO_(2)`
    C
    `CH_(3)CH_(2)Cl+H_(2)O+SO_(2)`
    D
    `CH_(3)COCl+HCl+SO_(2)`

  • When ethyl alcohol reacts with thionyl chloride in the presence of pyridine, the. product obtained is

    A
    `CH_3CH_2Cl+HCl`
    B
    `C_2H_5Cl+HCl + SO_2`
    C
    `CH_3CH_2Cl + H_2O + SO_2`
    D
    `H_3CH_2Cl + Cl_2 + SO_2`

  • Trityl chloride (Ph_(3)C Cl) is allowed to react with ethyl alcohol in the presence of pyridine.The product formed is

    A
    `Ph_(3)COCH_(2)CH_(3)`
    B
    `Ph_(3)C-OH`
    C
    `PH_(3)C CH = CH_(2)`
    D
    `CH_(3)CH_(2)Cl`
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